Influence of ventilation in HS exposure and emissions from a gravity sewer.

This study was carried out to evaluate the effect of natural ventilation and intermittent pumping events in hydrogen sulfide and methane dynamics, in terms of system operation and risk of gas exposure. Work was conducted in a full scale gravity sewer downstream of pumping stations, in Portugal. Different ventilation rates and locations were assessed, as well as HS removal rates and potential exposure risk, through the opening of distinct manhole covers.

Understanding the effect of ventilation, intermittent pumping and seasonality in hydrogen sulfide and methane concentrations in a coastal sewerage system.

Gas pollutants emitted during wastewater transport contribute to atmospheric pollution, aggravated risks for utility workers, infrastructure corrosion, and odour nuisance. Field studies have shown that is difficult to effectively obtain reliable correlations between in-sewer air movement and gas pollutant concentrations. This study aimed at investigating the influence of different ventilation and operating conditions in HS and CH horizontal and vertical movement in a section of a gravity sewer, downstream of a pumping station.

Liquid-Gas Mass Transfer of Volatile Substances in an Energy Dissipating Structure.

  Mass transfer of a range of volatile substances was studied under highly turbulent conditions. The applied setup mimicked drop structures, where the release of volatile organic carbons likely occurs at a high rate. The experiments covered several substances in a range of resistances from residing entirely in the liquid film to being fully in the gas film.

Release of hydrogen sulfide under intermittent flow conditions - the potential of simulation models.

For engineering purposes it is especially useful to be able to predict and control sewer corrosion rates and odor impacts as well as to design effective measures aiming to reduce effects related to hydrogen sulfide formation and release. Doing so, it is important to use modeling tools that are capable of assessing variations of dissolved oxygen, dissolved sulfide and hydrogen sulfide gas concentrations for a wide range of environmental scenarios. Two such models were assessed: AEROSEPT, an empirical formulation, and WATS, a conceptual and more complex approach.

Assessment of sulfide production in a full scale wastewater sludge rising main.

Production and build-up of sulfide in wastewater systems, especially downstream of rising mains, may lead to severe odour nuisance, toxic environments and high risk of corrosion. Due to increased population migration towards cities and lower area availability for treatment facilities, rising mains for the conveyance of wastewater sludge are becoming more frequent, and research on sulfide build-up in such cases is needed. In this paper the findings of the work carried out in a full scale wastewater sludge rising main, operated during different seasons and under distinct conditions are presented (comprising both the start-up and normal operation stages of the facility).

Erratum: Water Science and Technology 75 (10), 2257-2267: Liquid-gas mass transfer at drop structures, Natércia Matias, Asbjørn Haaning Nielsen, Jes Vollertsen, Filipa Ferreira and José Saldanha Matos, doi: 10.2166/wst.2017.103.

Over the last decades, considerable progress has been made in the understanding of the sulfur cycle in sewer systems. In spite of a wealth of experimental and field studies that have addressed the release of hydrogen sulfide from free surface flows in gravity sewers and the corresponding air-water mass transfer, little is known about hydrogen sulfide emission under highly turbulent conditions (e.g.

Liquid-gas mass transfer at drop structures.

Over the last decades, considerable progress has been made in the understanding of the sulfur cycle in sewer systems. In spite of a wealth of experimental and field studies that have addressed the release of hydrogen sulfide from free surface flows in gravity sewers and the corresponding air-water mass transfer, little is known about hydrogen sulfide emission under highly turbulent conditions (e.g.

Release of hydrogen sulfide in a sewer system under intermittent flow conditions: the Eiceira case study, in Portugal.

The presence and fate of hydrogen sulfide in wastewater systems were studied in two stretches of an intercepting sewer system located in a coastal village, in Portugal. A range of hydraulic parameters were obtained and liquid and gas phase measurements were carried out, both continuously and through intensive sampling campaigns. Upstream, where flow rates were relatively low, dissolved sulfide concentrations around 12 mg S L and hydrogen sulfide gas concentrations above 250 ppm were observed, along with limited corrosion damage.

Dynamic Modeling of Hydrogen Sulfide within Enclosed Environments in Biosolids Recovery Facilities.

  Hydrogen sulfide emissions from wastewater affect human health and equipment durability, thus presenting a complex issue for utilities. Several VOC emission models have been used before to predict H2S in collection systems and water resources recovery operations, even if with restrictions. By contrast, fewer studies focus on biosolids emissions and modelling.

Calibration Transfer Between a Bench Scanning and a Submersible Diode Array Spectrophotometer for In Situ Wastewater Quality Monitoring in Sewer Systems.

Online monitoring programs based on spectroscopy have a high application potential for the detection of hazardous wastewater discharges in sewer systems. Wastewater hydraulics poses a challenge for in situ spectroscopy, especially when the system includes storm water connections leading to rapid changes in water depth, velocity, and in the water quality matrix. Thus, there is a need to optimize and fix the location of in situ instruments, limiting their availability for calibration.

Heats of mixing using an isothermal titration calorimeter: associated thermal effects.

The correct determination of the energy generated or absorbed in the sample cell of an Isothermal Titration Calorimeter (ITC) requires a thorough analysis of the calorimetric signal. This means the identification and quantification of any thermal effect inherent to the working method. In this work, it is carried out a review on several thermal effects, studied by us in previous work, and which appear when an ITC is used for measuring the heats of mixing of liquids in a continuous mode.