Improved Conductivity in Gellan Gum and Montmorillonite Nanocomposites Electrolytes.

Nanocomposite polymer electrolytes (NPEs) were obtained using gellan gum (GG) and 1 to 40 wt.% of montmorillonite (NaSYN-1) clay. The NPEs were crosslinked with formaldehyde, plasticized with glycerol, and contained LiClO.

Structural ordering in Cd(x)Pb(1-x)F2 alloys: a combined molecular dynamics and solid state NMR study.

Molecular dynamics (MD) simulations of binary Cd(x)Pb(1-x)F(2) alloys have been carried out, using a two-body Buckingham interaction potential, leading to a correct description of structural properties as a function of composition and pointing towards an understanding of the eutectic phenomenon. The simulation data can be analyzed in terms of five local fluorine environments Q((n)) (4> or =n> or =0), where n is the number of Pb nearest-neighbor environments. The results suggest a highly nonstatistical population distribution, suggesting an intrinsic phase segregation tendency in the undercooled melt, during the cooling process.