Chemical Reduction of Nitrate by Zero-Valent Iron: Shrinking-Core versus Surface Kinetics Models.

Zero valent iron (ZVI) is being used in permeable reactive barriers (PRB) for the removal of oxidant contaminants, from nitrate to chlorinated organics. A sound design of these barriers requires a good understanding of kinetics. Here we present a study of the kinetics of nitrate reduction under relatively low values of pH, from 2 to 4.

Anaerobic co-digestion of municipal sewage sludge and fruit/vegetable waste: effect of different mixtures on digester stability and methane yield.

The anaerobic co-digestion of fruit and vegetable waste (FVW) and municipal sewage sludge (MSS) is investigated under mesophilic conditions. This was done at a constant hydraulic retention time (HRT) similar to that typically used at waste water treatment plant digesters, 20 days. The effects on digester performance of the FVW:MSS ratio and the organic loading rate (OLR) were examined.

Quantification of methane emissions in a Mediterranean landfill (Southern Spain). A combination of flux chambers and geostatistical methods.

In this study, landfill gas emissions from a landfill located in southern Spain were estimated using static surface flux chambers and applying and comparing four geostatistical methods; ordinary kriging, lognormal kriging, intrinsic random functions of order K and indicator kriging. This paper presents the methodology used to calculate methane (and carbon dioxide) emissions from a landfill in southern Spain. Static flux chambers were used to estimate emissions through the sealing layer of a landfill assuming that the geospatial mean best expresses the average value of these emissions.

Production of biogas from co-digestion of livestock and agricultural residues: A case study.

This study was undertaken to determine the possible changes in the digester yield and performance for the anaerobic co-digestion under mesophilic conditions of strawberry residues (SRs) together with pig manure (PM). The first part of this paper deals with the digestion of SR as a single substrate. For organic loading rates (OLRs) of 4.

Mobility and fate of carbetamide in an agricultural soil.

The objective of this work is to gain a better understanding of the fate of carbetamide, as a representative herbicide, after its soil application. To reach this goal, batch and column laboratory experiments were performed and a transport model was proposed consistent with these results. Then field-scale experiments were carried out for two years and the results compared with those that would be obtained from the transport model, once the degradation terms were introduced.

Two-dimensional model for soil electrokinetic remediation of heavy metals. Application to a copper spiked kaolin.

A two-dimensional numerical model has been developed to simulate the electrokinetic remediation of soils contaminated with heavy metals and has been validated using laboratory experiments performed with a copper spiked kaolin. The model divides the soil into compartments in a Cartesian grid and a non-conductivity barrier encloses the considered area. Basically, it consists in two main parts clearly distinguishable.