Creep measurements confirm steady flow after stress maximum in extension of branched polymer melts.

We provide conclusive evidence of nonmonotonic mechanical behavior in the extension of long-chain branched polymer melts. While nonmonotonic behavior is known to occur for solids, for the case of polymeric melts, this phenomenon is in direct contrast with current theoretical models. We rule out the possibility of the overshoot being an experimental artifact by confirming the existence of steady flow after a maximum in the ratio of stress to strain rate versus strain under both constant stress and constant strain-rate kinematics.

3D Simulation of Nano-Imprint Lithography.

A proof of concept study of the feasibility of fully three-dimensional (3D) time-dependent simulation of nano-imprint lithography of polymer melt, where the polymer is treated as a structured liquid, has been presented. Considering the flow physics of the polymer as a structured liquid, we have followed the line initiated by de Gennes, using a Molecular Stress Function model of the Doi and Edwards type. We have used a 3D Lagrangian Galerkin finite element methods implemented on a parallel computer architecture.