This paper presents the results of a research aimed at establishing a novel method for the detection of primary and secondary micro- and nanoplastics (MNPs), by using the fluorescence properties of the dye Nile Red-n-heptane (NR-H). The method has been applied to the detection of laboratory degraded polymers (Polystyrene, PS and Polyethylene Terephthalate, PET) as well as traceable latex microspheres in aqueous environments, showing a remarkable detection capacity and avoiding the prior extraction or processing of MNPs in natural samples, with significant time savings compared to conventional methods. The study has been carried out on various types of water, including samples from wastewater treatment plants, boreholes, seawater and synthesized seawater.
View Article and Find Full Text PDFThis Special Issue of the journal arises from the need to highlight the developments in the field of membrane research and membrane processes that have been emerging in recent years by researchers and research groups based in the Iberian Peninsula [...
View Article and Find Full Text PDFThis scientific publication presents a novel modification of the liquid-liquid displacement porosimetry (LLDP) method, aiming for the non-destructive automated analysis of water purification membrane filtration devices in the microfiltration (MF) and ultrafiltration (UF) range. The technical adaptation of LLDP enables the direct in-line porosimetric analysis of commercial filtration devices, avoiding the filtration devices' destruction. Six commercially available filtration devices with polyethersulfone (PES) and polysulfone (PS) membranes were studied using an improved device developed by the IFTS, which was based on a commercial LLDP instrument.
View Article and Find Full Text PDFMembrane dialysis is studied as a promising technique for partial dealcoholization of white wines. The performance of three membrane processes applied for the partial dealcoholization of white wines of the Verdejo variety has been studied in the present work. Combination of Nanofiltration with Pervaporation, single step Pervaporation and, finally, Dialysis, have been applied to white wines from same variety and different vintages.
View Article and Find Full Text PDFThis works aims to study the porous characterization of several commercial Gas Diffusion Layers (GDL). Three carbon-based porous GDL featuring a highly rigid microstructure of interconnected pores of several manufacturers were analyzed. Gas Liquid Displacement Porometry (GLDP) and Liquid Extrusion Porometry (LEP) have been used to obtain their pore size distributions (PSD) and the mean and mode pore diameters ( and ), by means of a gas/liquid and extrusion porometer developed at IFTS.
View Article and Find Full Text PDFThe following review aims at analyzing the contribution of Spanish researchers to membrane science and technology, with a historical compilation of the main milestones. We used a bibliometric analysis based on the Scopus database (1960-2020) dealing with 8707 documents covering the different disciplines and subject areas where membranes are involved. Furthermore, the information has been updated to the present moment of writing this manuscript in order to include the latest research lines and the different research groups currently active in Spain, which may lead the way to the development of the field in the coming years.
View Article and Find Full Text PDFThis works aims to propose and demonstrate the accuracy of a novel method of characterization aimed for non-destructive analysis of microfiltration (MF) membrane cartridges. The method adapts conventional liquid-liquid displacement porosimetry (LLDP) for performing an in-line porosimetric analysis of the membrane cartridges, getting their pore size distributions (PSDs) and mean pore diameters (). Six commercial filtration cartridges featuring polyethersulfone (PES) pleated membranes were analyzed using a newly designed filtration rig, based on the liquid-liquid displacement porometer, developed at the Institut de la Filtration et des Techniques Séparatives (IFTS) and operated at constant flow.
View Article and Find Full Text PDFA commercial ultrafiltration (UF) membrane (HFM-183 de Koch Membrane Systems) made of poly(vinylidene fluoride) (PVDF), was recovered with a negatively-charged polyelectrolyte (poly(sodium 4-styrenesulfonate)) (PSS), and the effects on its electric, chemical, and morphological properties were analyzed. Atomic force microscopy (AFM), liquid-liquid displacement porometry, Electrical Impedance Spectroscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy were used to investigate the modifications induced by the deposition of PSS on the PVDF positively-charged membrane and after its treatment by a radio frequency Ar-plasma. These techniques confirmed a real deposition and posterior compaction of PSS with increasing roughness and decreasing pore sizes.
View Article and Find Full Text PDFBackground: In randomised studies, the capsaicin 8% patch has demonstrated effective pain relief in patients with peripheral neuropathic pain (PNP) arising from different aetiologies.
Methods: ASCEND was an open-label, non-interventional study of patients with non-diabetes-related PNP who received capsaicin 8% patch treatment, according to usual clinical practice, and were followed for ≤52 weeks. Co-primary endpoints were percentage change in the mean numeric pain rating scale (NPRS) 'average daily pain' score from baseline to the average of Weeks 2 and 8 following first treatment; and median time from first to second treatment.
Purpose: Physical activity training programs in older adults have recognized health benefits. Evidence suggests that training should include a combination of progressive resistance, balance, and functional training. Our aim was to assess the effects of a simple physical activity program working on strength, flexibility, cardiovascular fitness, and balance in older adults, as well as the effects of a detraining period, at various different ages.
View Article and Find Full Text PDFThe efficacy of long-term intake of a novel functional food supplement Funciona™ containing vitamins and juiced fruits was evaluated in order to assess the net effect of physical activity and antioxidant potentials in healthy older adult population. The long-term (2 years) and large-scale (400 older adult subjects) interventional study was based on both moderate-intensity exercise practice and concurrent supplementation. Sustained exercise-induced oxidative stress as reflected in significantly increased blood thiobarbituric acid-reactive substances (TBARS) (+15%), protein carbonyl groups (PC) (+18%) and oxidized glutathione (GSSG) (+112%) concentrations, and leukocyte 8-OHdG contents (23%).
View Article and Find Full Text PDFFree radicals and oxidative stress are involved in the pathogenic mechanisms of cardiovascular disease (CVD), diabetes and cancer. Exercise is a useful strategy for preventing CVD but in elderly persons it can enhance oxidative stress, which is why some studies recommend antioxidant supplementation for exercising elderly subjects. This intervention study was performed on 320 elderly subjects following a Geriatric Revitalization Program (GEREPRO) to maintain physical health and reduce CVD risk.
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