This work explores the use of Kraft lignins sourced from different poplar genotypes ( L. "PO-10-10-20" and × "Ballotino") isolated by selective acid precipitation (at pHs 5 and 2.5) to produce electrospun nanostructures that can be further employed for structuring vegetable oils.
View Article and Find Full Text PDFDeveloping gelled environmentally friendly dispersions in oil media is a hot topic for many applications. This study aimed to investigate the production of electrospun cellulose triacetate (CTA) nanofibers and to explore their potential application as a thickening agent for castor oil. The key factors in the electrospinning process, including the intrinsic properties of CTA solutions in methylene chloride (DCM)/ethanol (EtOH), such us the shear viscosity, surface tension, and electrical conductivity, were systematically studied.
View Article and Find Full Text PDFThis work describes the chemical and structural characterization of a lignin-rich residue from the bioethanol production of olive stones and its use for nanostructures development by electrospinning and castor oil structuring. The olive stones were treated by sequential acid/steam explosion pretreatment, further pre-saccharification using a hydrolytic enzyme, and simultaneous saccharification and fermentation (PSSF). The chemical composition of olive stone lignin-rich residue (OSL) was evaluated by standard analytical methods, showing a high lignin content (81.
View Article and Find Full Text PDFChalcogenides semiconductors are currently being studied as active layers in the development of electronic devices in the field of applied technology. In the present paper, cadmium sulfide (CdS) thin films containing nanoparticles of the same material as the active layer were produced and analyzed for their application in fabricating optoelectronic devices. CdS thin films and CdS nanoparticles were obtained via soft chemistry at low temperatures.
View Article and Find Full Text PDFWe formulated and characterized oleogels based on montmorillonite clay and vegetable oils that could serve as eco-friendly semi-solid lubricants. In particular, we studied the influence of the physical-chemical properties of olive, castor, soybean, linseed, and sunflower oils on the rheological, chemical, thermal, and tribological properties of the semi-solid lubricants. We prepared the oleogels via the highly intensive mixing of vegetable oils with clay at a concentration of 30 wt.
View Article and Find Full Text PDFThis work focuses on the structural features and physicochemical properties of different Kraft lignins and how they can influence the electrospinning process to obtain nanostructures. Structural features of Kraft lignins were characterized by nuclear magnetic resonance, size exclusion chromatography, fourier-transform infrared spectroscopy, and thermal analysis, whereas chemical composition was analyzed by standard method. The addition of cellulose acetate (CA) improves the electrospinning process of Kraft lignins (KL).
View Article and Find Full Text PDFIn the last few years, electrospinning has proved to be one of the best methods for obtaining membranes of a micro and nanometric fiber size. This method mainly consists in the spinning of a polymeric or biopolymeric solution in solvents, promoted by the difference in the electric field between the needle and collector, which is finally deposited as a conjunction of randomly oriented fibers. The present work focuses on using cellulose derivatives (namely cellulose acetate and ethylcellulose), based on the revaluation of these byproducts and waste products of biorefinery, to produce nanostructured nanofiber through electrospinning with the objective of establishing a relation between the initial solutions and the nanostructures obtained.
View Article and Find Full Text PDFHydrogels are considered good biomaterials for soft tissue regeneration. In this sense, collagen is the most used raw material to develop hydrogels, due to its high biocompatibility. However, its low mechanical resistance, thermal stability and pH instability have generated the need to look for alternatives to its use.
View Article and Find Full Text PDFThe present work focuses on the development of lignin micro- and nano-structures obtained by means of electrohydrodynamic techniques aimed to be potentially applicable as thickening or structuring agents in vegetable oils. The micro- and nano-structures used were mainly composed of eucalyptus kraft lignin (EKL), which were doped to some extent with polyvinylpyrrolidone (PVP). EKL/PVP solutions were prepared at different concentrations (10-40 wt.
View Article and Find Full Text PDFThe present work focuses on the development of scaffolds based on gelatin and chitosan using different protocols based on the general processing of phase separation, derived from the fabrication of hydrogels and freeze-drying. The scaffolds were produced with 1 wt% of two different biopolymers, i.e.
View Article and Find Full Text PDF