Composite electronic materials based on poly(3,4-propylenedioxythiophene) and highly charged poly(aryleneethynylene)-wrapped carbon nanotubes for supercapacitors.

Supercapacitor charge storage media were fabricated using the semiconducting polymer poly(3,4-propylenedioxythiophene) (PProDOT) and single-walled carbon nanotubes (SWNTs) that were helically wrapped with ionic, conjugated poly[2,6-{1,5-bis(3-propoxysulfonicacidsodiumsalt)}naphthylene]ethynylene (PNES). These PNES-wrapped SWNTs (PNES-SWNTs) enable efficient dispersion of individualized nanotubes in a wide range of organic solvents. PNES-SWNT film-modified Pt electrodes were prepared by drop casting PNES-SWNT suspensions in MeOH; high stability, first-generation PProDOT/PNES/SWNT composites were realized via electropolymerization of the ProDOT parent monomer (3,4-propylenedioxythiophene) in a 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide/propylene carbonate solution at the PNES-SWNT-modified electrode.

Electrical characterization of a single electrospun porous nanostructured tin oxide ribbon.

A single nanostructured porous tin oxide ribbon, with its length, width and thickness of more than 1 mm, around 20 microm and around 20 nm, respectively, were fabricated using electrospinning, and electrically characterized in a temperature range between 300 K and 90 K, a magnetic field range from -9 to 9 T (negative sign stands for the reverse direction), and the environment of air and vacuum. The electrical conductivity (sigma) of the ribbon was found insensitive to magnetic field, but sensitive to temperature and environment. Its response time to air evacuation is 67+7 s.

Field effect devices and sensors based on electrospun polymer assisted tin oxide nanoribbons.

Electrospinning is presented as a facile method of preparing relatively long tin oxide (SnO2) nanofibers that are robust and stable in air. Upon heat treatment, the fibers collapse into a ribbon-like structure with surfaces that are not smooth, rather, are marked with several interconnected pathways. These nanoribbons were electrically characterized in a field effect transistor configuration in vacuum, with and without ultra violet (UV) light exposure.

Bioconjugation of alkaline phosphatase to mechanically processed, aqueous suspendible electrospun polymer nanofibers for use in chemiluminescent detection assays.

Aqueous suspendible polymer nanostructures were prepared by simple microtome processing of electrospun nylon 6 nanofibers and were used to immobilize calf intestinal alkaline phosphatase (ALP) by either covalent or noncovalent bioconjugation chemistries. It was found that noncovalent immobilization of ALP to the mechanically cut nanofibers (mean length approximately 4 microm; mean diameter approximately 80 nm) using a multi-stacked, layer-by-layer (LBL) approach with the cationic polymer Sapphire II resulted in the highest enzyme loading (48.1 +/- 0.