Correction: Iridium-(κ-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance.

Correction for 'Iridium-(κ-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance' by Alejandra Gomez-España , , 2023, , 6722-6729, https://doi.org/10.1039/d3dt00744h.

Correction: Iridium-(κ-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance.

Correction for 'Iridium-(κ-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance' by Alejandra Gomez-España , , 2023, https://doi.org/10.1039/d3dt00744h.

Iridium-(κ-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance.

The iridium(III) complexes [Ir(H)(Cl)(κ-NSi)(κ-bipy)] (2) and [Ir(H)(OTf)(κ-NSi)(κ-bipy)] (3) (NSi = {4-methylpyridine-2-yloxy}ditertbutylsilyl) have been synthesized and characterized including X-ray studies of 3. A comparative study of the catalytic activity of complexes 2, 3, [Ir(H)(OTf)(κ-NSi)(coe)] (4), and [Ir(H)(OTf)(κ-NSi)(PCy)] (5) (0.1 mol%) as catalysts precursors for the solventless formic acid dehydrogenation (FADH) in the presence of EtN (40 mol%) at 353 K has been performed.