Compact embedded device for lock-in measurements and experiment active control.

We present a multi-purpose toolkit for digital processing, acquisition, and feedback control designed for physics labs. The kit provides in a compact device the functionalities of several instruments: function generator, oscilloscope, lock-in amplifier, proportional-integral-derivative filters, ramp scan generator, and a lock-control. The design combines field-programmable-gate-array processing and microprocessor programing to get precision, ease of use, and versatility.

Rate measurement of the reaction of CF2Cl radicals with O2.

We have studied the association reaction of the CF(2)Cl radicals with O(2) in presence of N(2). The infrared multiple photon dissociation (IRMPD) technique with a homemade TEA CO(2) laser was used for the CF(2)Cl radical generation and the vibrational chemiluminiscence technique was set up for the study of the reaction kinetics. The time-resolved IR fluorescence of the vibrationally excited CF(2)O photoproduct was used to measure the disappearance rate of these radicals.

Chloroform infrared multiphoton dissociation in the presence of O2 and NO2.

The infrared multiphoton dissociation (IRMPD) of CDCl3 in the presence of O2 and NO2 as acceptor gases has been studied. We have worked with both pure CDCl3 and mixtures with CHCl3. The reaction mechanism following IRMPD of CDCl3 is discussed in detail.

Laser flash photolysis in a O3/Cl2 mixture at 266 nm in a very low-pressure flow system.

The laser flash photolysis in a very low-pressure flow system with mass spectrometry detection technique was developed for the study of oxidation reactions of chlorofluorocarbons. In this work, we have studied the UV photolysis of O3 in the presence of Cl2 at room temperature, which presents two catalytic cycles of O3 depletion with efficiencies dependent on the partial pressures in the photoreactor. The ozone dissociation was initiated with fourth harmonic pulses of a Nd:YAG laser.