Gas Phase Reactions of Ions Derived from Anionic Uranyl Formate and Uranyl Acetate Complexes.

The speciation and reactivity of uranium are topics of sustained interest because of their importance to the development of nuclear fuel processing methods, and a more complete understanding of the factors that govern the mobility and fate of the element in the environment. Tandem mass spectrometry can be used to examine the intrinsic reactivity (i.e.

Collision-induced dissociation of uranyl-methoxide and uranyl-ethoxide cations: Formation of UO2 H(+) and uranyl-alkyl product ions.

Rationale: The lower levels of adventitious H2 O in a linear ion trap allow the fragmentation reactions of [UO2 OCH3 ](+) and [UO2 OCH2 CH3 ](+) to be examined in detail.

Methods: Methanol- and ethanol-coordinated UO2 (2+) -alkoxide precursors were generated by electrospray ionization (ESI). Multiple-stage tandem mass spectrometry (MS(n) ) and collision-induced dissociation (CID) were performed using a linear ion trap mass spectrometer.

Apparent activation of H2O and elimination of H2 from gas-phase mixed-metal complexes containing silver, calcium and deprotonated glycine.

Rationale: Ion trap mass spectrometry was used to study the reactivity of species derived from gas-phase, mixed-metal complexes, [Ag2 Xx(Gly-H)3 ](+) , where Xx = Ca, Mg, Sr and Ag, and in particular the apparent activation of an H2 O ligand added during an ion-molecule reaction.

Methods: Precursor [Ag2 Xx(Gly-H)3 ](+) complexes were formed by electrospray ionization (ESI) using spray solutions in which AgNO3 , XxNO3 and glycine were mixed in a 1:1:3 molar ratio. Specific species for study of ion-molecule reactions were created in a "top down" fashion using collision-induced dissociation (CID).