Publications by authors named "Jordan Alysia Barr"
Article Synopsis
- - Fe-N-C single-atom catalysts (SACs) have impressive peroxidase-like activity, mimicking natural enzymes due to isolated iron sites on a carbon substrate.
- - Introducing phosphorus (P) heteroatoms into the carbon matrix of these SACs enhances their catalytic activity, with a specially designed 1D carbon nanowire catalyst showing better performance and stability.
- - While a small amount of P significantly boosts POD-like activity, excessive P doesn't contribute further; this enhanced catalyst is successfully used for sensitive detection of acetylcholine.
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Article Synopsis
- Fe-N-C single-atomic metal site catalysts (SACs) are being explored as alternatives to platinum-based catalysts for oxygen reduction reactions in fuel cells.
- Researchers aim to enhance the efficiency of these catalysts by modifying the electronic structure of their active sites, particularly through the use of heteroatom doping.
- The study introduces chlorine as a near-range coordinator to improve the Fe-N active center, resulting in a catalyst (FeNCl SAC) that shows higher ORR activity compared to traditional FeN SAC, supported by theoretical calculations and experimental results.
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