Predictive Synthesis of Transition Metal Carbide via Thermochemical Oxocarbon Equilibrium.

Fabricating nanoscale metal carbides is a great challenge due to them having higher Gibbs free energy of formation (Δ) values than other metal compounds; additionally, these carbides have harsh calcination conditions, in which metal oxidation is preferred in the atmosphere. Herein, we report oxocarbon-mediated calcination for the predictive synthesis of nanoscale metal carbides. The thermochemical oxocarbon equilibrium of CO-CO reactions was utilized to control the selective redox reactions in multiatomic systems of Mo-C-O, contributing to the phase-forming and structuring of Mo compounds.

Floating-Harbor Syndrome in a Korean Patient with Short Stature and Early Puberty: A Case Report.

Floating-Harbor syndrome (FHS) is a rare autosomal dominant genetic disorder characterized by proportionately short stature, lack of expressive language, and distinctive facial features, including a large nose, long eyelashes, deeply set eyes, and a triangular face. We present a case of an 11-year-old Korean girl who was initially suspected of having Noonan-like syndrome but was later diagnosed with Floating-Harbor syndrome. The patient exhibited short stature, developmental language delay, dysmorphic facial features, and early puberty.

Scaling behavior and text cohesion in Korean texts.

This study examines whether different types of texts, particularly in Korean, can be distinguished by the scaling exponent and degree of text cohesion. We use the controlled growth process model to incorporate the interaction effect into a power-law distribution and estimate the implied parameter explaining the degree of text cohesiveness in a word distribution. We find that the word distributions of Korean languages differ from English regarding the range of scaling exponents.