Impact of particle size and oxide phase on microplastic transport through iron oxide-coated sand.

The presence of microplastics in aquatic environments threatens the ecological system and human health. This study investigates the transport and retention of polystyrene microplastics (PSMPs) in clean sand, and hematite-, goethite-, and magnetite-coated iron oxide - sands as a function of size ratio and ionic strength. The breakthrough curves (BTCs), retention profiles, and hydraulic pressure were measured through soil-column experiments, and the retention of PSMPs was assessed from the observed BTCs, RPs and first-order attachment coefficients.

A framework for estimating soil water characteristic curve and hydraulic conductivity function of permeable reactive media.

The unsaturated behavior of permeable reactive barriers (PRB) is a critical component in predicting the removal efficiency through the adsorption of contaminants. This study investigates the framework to estimate the soil water characteristic curve (SWCC) and hydraulic conductivity function (HCF) for iron oxide-coated sand (IOCS) and zeolite, which are common materials used in PRBs. A multistep outflow (MSO) experiment was performed and the results of the MSO experiment were used to optimize associated parameters in Kosugi's SWCC and HCF.

Thermal conductivity of dry fly ashes with various carbon and biomass contents.

Recently, sustainable energy portfolios have added biomass combustion and coal/biomass co-combustion as alternative fuel sources for generation of electricity. Fly ashes that result from combustion of biomass or its co-combustion with coal contain relatively high contents of unburned carbon, while increasingly stringent air quality regulations have also increased the residual carbon content in fly ash produced by coal combustion alone. While previous studies documented the mechanical and chemical behavior of fly ash relatively well, the thermal characteristics of those fly ashes have not been well studied.

Evolution of Small Strain Soil Stiffness during Freeze-Thaw Cycle: Transition from Capillarity to Cementation Examined Using Magnetic and Piezo Crystal Sensors.

Freeze-thaw cycles caused by seasonal temperature fluctuations significantly affect the geotechnical engineering properties. This study investigated the crucial role of water distribution patterns in the characterization of elastic wave properties for the fine F-110 sand during a freeze-thaw cycle. Sand specimens with four different water distribution patterns were prepared, namely homogeneously-mixed, evaporation-driven, vertically-, and horizontally-layered specimens.

An experimental study of cotransport of heavy metals with kaolinite colloids.

Cotransport of heavy metals, Pb, Cu and Zn (multi-metal system), and transport of those metals (single-metal system) were investigated by performing laboratory soil column experiment under the presence of kaolinite colloids. Preequilibrated kaolinite colloids with heavy metal solution was injected to the column until 10 pore volumes under two different flow rates and three different concentration of kaolinite colloids. Heavy metal concentration in effluent showed that the mobility of Pb was facilitated as kaolinite colloids concentration (C) increases under high flow rate while the mobility of Pb and Cu were retarded as C increases under low flow rate.

Role of Immobile Kaolinite Colloids in the Transport of Heavy Metals.

Predicting the transport of contaminants in porous media is crucial to protecting public health and remediating contaminated soil and groundwater. However, the prediction of contaminant transport is challenging due to the presence of mobile and immobile colloids. The work performed in this experimental investigation quantified the role of immobile clay colloids on metal transport through sets of column breakthrough experiments under varying solution chemistry, clay content, and flow rate.