Atomic-scale defects can control the exploitable optoelectronic performance of crystalline materials, and several point defects in diamond are emerging functional components for a range of quantum technologies. Nitrogen and hydrogen are common impurities incorporated into diamond, and there is a family of defects that includes both. The NVH defect is a lattice vacancy where three nearest neighbor carbon atoms are replaced with nitrogen atoms and a hydrogen is bonded to the remaining carbon.
View Article and Find Full Text PDFPhys Chem Chem Phys
June 2011
The low mass of hydrogen leads to highly localised, high-frequency vibrational modes associated with H-containing defects in crystalline materials. In addition to vibrational spectroscopy, the presence of hydrogen in diamond has been identified from several experimental techniques. In particular, paramagnetic resonance shows that H is often associated with lattice vacancies, but in many cases the microscopic structure of the defects remains to be determined.
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