Material Characterization and Electrochemical Properties of Titanium Alloy 5553 Prepared by Selective Laser Melting as Processed and after Abrading and Polishing.

The microstructure, Vickers microhardness, and electrochemical properties of an additive manufactured titanium alloy, Ti-5553 (Ti-5Al-5Mo-5V-3Cr wt %), are reported on. The alloy specimens were fabricated by selective laser melt processing. The surface morphology and electrochemical properties of the as-processed and surface-pretreated (abraded and polished) Ti-5553 specimens were investigated.

A simple simulation-derived descriptor for the deposition of polymer-wrapped carbon nanotubes on functionalized substrates.

Controlling the deposition of polymer-wrapped single-walled carbon nanotubes (s-CNTs) onto functionalized substrates can enable the fabrication of s-CNT arrays for semiconductor devices. In this work, we utilize classical atomistic molecular dynamics (MD) simulations to show that a simple descriptor of solvent structure near silica substrates functionalized by a wide variety of self-assembled monolayers (SAMs) can predict trends in the deposition of s-CNTs from toluene. Free energy calculations and experiments indicate that those SAMs that lead to maximum disruption of solvent structure promote deposition to the greatest extent.

Graphene nanoribbons initiated from molecularly derived seeds.

Semiconducting graphene nanoribbons are promising materials for nanoelectronics but are held back by synthesis challenges. Here we report that molecular-scale carbon seeds can be exploited to initiate the chemical vapor deposition (CVD) synthesis of graphene to generate one-dimensional graphene nanoribbons narrower than 5 nm when coupled with growth phenomena that selectively extend seeds along a single direction. This concept is demonstrated by subliming graphene-like polycyclic aromatic hydrocarbon molecules onto a Ge(001) catalyst surface and then anisotropically evolving size-controlled nanoribbons from the seeds along [Formula: see text] of Ge(001) via CH CVD.

Aligned 2D carbon nanotube liquid crystals for wafer-scale electronics.

Semiconducting carbon nanotubes promise faster performance and lower power consumption than Si in field-effect transistors (FETs) if they can be aligned in dense arrays. Here, we demonstrate that nanotubes collected at a liquid/liquid interface self-organize to form two-dimensional (2D) nematic liquid crystals that globally align with flow. The 2D liquid crystals are transferred onto substrates in a continuous process generating dense arrays of nanotubes aligned within ±6°, ideal for electronics.

Chemical and topographical patterns combined with solution shear for selective-area deposition of highly-aligned semiconducting carbon nanotubes.

Selective deposition of semiconducting carbon nanotubes (s-CNTs) into densely packed, aligned arrays of individualized s-CNTs is necessary to realize their potential in semiconductor electronics. We report the combination of chemical contrast patterns, topography, and pre-alignment of s-CNTs shear to achieve selective-area deposition of aligned arrays of s-CNTs. Alternate stripes of surfaces favorable and unfavorable to s-CNT adsorption were patterned with widths varying from 2000 nm down to 100 nm.

Treatment principles, prognostic factors and controversies in radial neck fractures in children: A systematic review.

Introduction: Radial Neck fractures are rare injuries in children. There is controversy surrounding their prognosis and management.

Aims: This review aims to produce an up-to-date summary to clarify prognostic factors and management principles, in the light of recent, better-quality evidence.

Can locking plate fixation of symphyseal disruptions allow early weight bearing?

Introduction: Anterior pubic symphyseal plate fixation is the recommended treatment for disruption of pubic symphysis in an unstable pelvic ring injury. The rigid construct offered by locking symphyseal plate has the theoretical advantage of allowing patients to weight bear early. However, there are concerns of catastrophic failure about the locked plate construct.

Solvent-Mediated Affinity of Polymer-Wrapped Single-Walled Carbon Nanotubes for Chemically Modified Surfaces.

Semiconducting single-walled carbon nanotube (s-CNT) arrays are being explored for next-generation semiconductor electronics. Even with the multitude of alignment and spatially localized s-CNT deposition methods designed to control s-CNT deposition, fundamental understanding of the driving forces for s-CNT deposition is still lacking. The individual roles of the dispersant, solvent, target substrate composition, and the s-CNT itself are not completely understood because it is difficult to decouple deposition parameters.

Substrate-Independent Approach to Dense Cleavable Polymer Brushes by Nitroxide-Mediated Polymerization.

High grafting density polymer brushes are grown on an inimer coating bearing nitroxide-mediated polymerization (NMP) inimers and glycidyl methacrylate (GMA). The inimer coating is cross-linked on the substrate to provide an initiator layer with needed stability during long exposure to organic solvents at moderate to high temperatures. Surface-initiated nitroxide-mediated polymerization (SI-NMP) is conducted to grow polystyrene (PS) brushes on the coating with a sacrificial layer designed to cleave the brushes.

Biomechanical investigation of two long bone growth modulation techniques by finite element simulations.

Implants used to correct pathological varus-valgus deformities (VVD) and leg length discrepancies (LLD) may not be optimized for the specific treatment, as suggested by their off-label use. Detailed analysis of this issue has been limited by the poorly understood mechanical behavior of the growing physis and ignorance of the loads acting on the implants. The aim of this study was to predict and compare the loading conditions of a growth modulation implant in VVD and LLD treatments.

Protein Adsorption to Charged Gold Nanospheres as a Function of Protein Deformability.

The corona that forms as protein adsorbs to gold nanospheres (AuNSs) is directly influenced by the surface chemistry of the AuNS. Tools to predict adsorption outcomes are needed for intelligent design of nanomaterials for biological applications. We hypothesized that the denaturation behavior of a protein might be a useful predictor of adsorption behavior to AuNSs, and used this idea to study protein adsorption to anionic citrate-capped AuNSs and to cationic poly(allylamine hydrochloride) (PAH) wrapped AuNSs.

Paediatric lower limb deformity correction with the Eight Plate: adverse events and correction outcomes of 126 patients from an international multicentre study.

No large multicentre studies have yet been published on tension-band-like implants such as the Eight Plate to treat limb-length discrepancies and varus valgus deformities in children. Therefore, we carried out a retrospective international multicentre study including 126 patients to assess outcomes and to reliably quantify the incidence of implant-related and growth-plate related adverse events (AEs). Correction was achieved in 66% of varus valgus deformities and in 59% of limb-length discrepancies and maintained in 85%.

Missed adolescent acetabular apophyseal avulsion with late hip dislocation.

Background: Chronic hip dislocation associated with acetabular apophyseal avulsion in adolescence is rare. Whilst superior acetabular rim fractures have a documented theoretical risk of hip instability, we have not found a case of chronic dislocation resulting from this.

Methods: We report a case of a 12-year-old healthy boy who initially sustained a missed right acetabular apophyseal avulsion after falling from a quad bike.

fMRI responses to Jung's Word Association Test: implications for theory, treatment and research.

Jung's Word Association Test was performed under fMRI conditions by 12 normal subjects. Pooled complexed responses were contrasted against pooled neutral ones. The fMRI activation pattern of this generic 'complexed response' was very strong (corrected Z scores ranging from 4.

Management of pubic symphysis diastasis with locking plates: a report of 11 cases.

Introduction: The optimal method of fixation of symphyseal disruptions in pelvic ring injuries and post-operative rehabilitation is still debated. Options include two-hole, multi-hole and multiplanar plates. Post-operative rehabilitation can range from non-weight bearing bilaterally to full weight-bearing with crutches.

Selective Kirschner wiring for displaced distal radial fractures in children.

Objectives: This study was designed to evaluate our departmental policy of plaster immobilization and selective Kirschner (K) wiring for the management of displaced distal radius fractures in children.

Methods: On a retrospective basis, we evaluated a consecutive series of 112 childhood displaced distal radius fractures (108 patients; 77 boys, 31 girls; mean age 10.5+/-2.

Psychological factors and treatment adherence behavior in patients with chronic heart failure.

Background: Chronic heart failure adversely affects 300,000 Australians. Symptom stabilization and prognosis are partially determined by patients following medical and lifestyle recommendations.

Methods: To test the hypothesis that depression, anxiety, and self-efficacy are independent predictors of such adherence, 115 predominantly male (70.

Sex crime recidivism. Evaluation of a sexual offender treatment program.

Evaluations of programs for sex offenders report mixed results, are costly, and require validation. This study examines recidivism following a sexual offender treatment program in an Australian male offender population over an average at-risk period of 5 years and 1 month in the community. The group format, cognitive-behavioral program was offered to a subgroup of adult male prisoners.