Production and characterization of starch-lignin based materials: A review.

In their pristine state, starch and lignin are abundant and inexpensive natural polymers frequently considered green alternatives to oil-based and synthetic polymers. Despite their availability and owing to their physicochemical properties; starch and lignin are not often utilized in their pristine forms for high-performance applications. Generally, chemical and physical modifications transform them into starch- and lignin-based materials with broadened properties and functionality.

Temperature responsive crosslinked starch-kraft lignin macromolecule.

Starch is a natural polymer with a relatively simple structure and limited solubility in water. Kraft lignin (KL) is a complex biopolymer obtained as a by-product from the delignification of wood and grasses. The present work reports developing a temperature-responsive high molecular weight macromolecule from crosslinking KL and starch (KLS).

One-pot synthesis of magnetic cellulose nanocrystal and its post-functionalization for doxycycline adsorption.

The composite of magnetite (FeO) and cellulose nanocrystal (CNC) is considered a potential adsorbent for water treatment and environmental remediation. In the current study, a one-pot hydrothermal procedure was utilized for magnetic cellulose nanocrystal (MCNC) development from microcrystalline cellulose (MCC) in the presence of ferric chloride, ferrous chloride, urea, and hydrochloric acid. The x-ray photoelectron spectroscopy (XPS), x-ray diffraction (XRD), and Fourier-transform infrared spectroscopy analysis confirmed the presence of CNC and FeO, while transmission electron microscopy (TEM) and dynamic light scattering (DLS) analysis verified their respective sizes (< 400 nm and ≤ 20 nm) in the generated composite.

Generation of Sulfonated Lignin-Starch Polymer and Its Use As a Flocculant.

This paper reports the polymerization of tall oil lignin (TOL), starch, and 2-methyl-2-propene-1-sulfonic acid sodium salt (MPSA), a sulfonate-containing monomer, in a three-component system to generate flocculants for colloidal systems. By utilizing the advanced H, COSY, HSQC, HSQC-TOCSY, and HMBC NMR techniques, it was confirmed that the phenolic substructures of TOL and the anhydroglucose unit of starch were covalently polymerized by the monomer to generate the three-block copolymer. The molecular weight, radius of gyration, and shape factor of the copolymers were fundamentally correlated to the structure of lignin and starch, as well as the polymerization outcomes.

Enhanced flocculation of aluminum oxide particles by lignin-based flocculants in dual polymer systems.

Lignin is an abundant phenolic polymer produced vastly in pulping processes that could be further valorized. In this work, anionic (AKLs) and cationic (CKLs) lignin-based polymers were made by polymerizing kraft lignin (KL) with acrylic acid (AA) or [2-(methacryloyloxy) ethyl] trimethyl-ammonium chloride (METAC), respectively. In the polymerization reactions, various molar ratios of AA or METAC to KL were applied to produce AKLs and CKLs with different characteristics.

Process development for tall oil lignin production.

The aim of this work was to study the production and characterization of tall oil lignin (TOL) from tall oil soap (TOS) of the kraft pulping process following a new process (i.e., LignoTall).

Electrosprayed Core⁻Shell Composite Microbeads Based on Pectin-Arabinoxylans for Insulin Carrying: Aggregation and Size Dispersion Control.

Aggregation and coalescence are major drawbacks that contribute to polydispersity in microparticles and nanoparticles fabricated from diverse biopolymers. This study presents the evaluation of a novel method for the direct, electrospray-induced fabrication of small, CaCl₂/ethanol-hardened low methoxy pectin/arabinoxylans composite microbeads. The electrospray method was evaluated to control particle size by adjusting voltage, flux, and crosslinking solution content of CaCl₂/ethanol.