Plasma-Induced Catalytic Conversion of Nitrogen and Hydrogen to Ammonia over Zeolitic Imidazolate Frameworks ZIF-8 and ZIF-67.

Microporous crystals have emerged as highly appealing catalytic materials for the plasma catalytic synthesis of ammonia. Herein, we demonstrate that zeolitic imidazolate frameworks (ZIFs) can be employed as efficient catalysts for the cold plasma ammonia synthesis using an atmospheric dielectric barrier discharge reactor. We studied two prototypical ZIFs denoted as ZIF-8 and ZIF-67, with a uniform window pore aperture of 3.

Metal-Organic Framework HKUST-1 Promotes Methane Hydrate Formation for Improved Gas Storage Capacity.

The large demand of natural gas consumption requires an effective technology to purify and store methane, the main component of natural gas. Metal-organic frameworks and gas hydrates are highly appealing materials for the efficient storage of industrially relevant gases, including methane. In this study, the methane storage capacity of the combination of methane hydrates and HKUST-1, a copper-based metal-organic framework, was studied using high pressure differential scanning calorimetry.

Separation of Light Gases from Xenon over Porous Organic Cage Membranes.

Herein, we demonstrate the successful synthesis and separation ability of CC3 porous organic cage membranes grown on tubular supports for light gases He, CO, CH, and Kr over xenon. CC3 membranes were synthesized using secondary seeded growth and displayed different separation performances depending on the crystal size, size distribution of the seeds, and membrane thickness. CC3 membranes as thin as ∼2.