Production and Assessment of Poly(Lactic Acid) Matrix Composites Reinforced with Regenerated Cellulose Fibres for Fused Deposition Modelling.

Additive manufacturing can be a valuable tool to process polymeric composites reinforced with bio-based fibres, extending their use and opening new opportunities for more environmentally friendly materials. In this work, poly(lactic acid) (PLA) composites reinforced with regenerated cellulose fibres (lyocell) were processed into novel filaments and used for 3D printing. The Young's modulus of the filaments increased with the addition of fibres, but substantial porosity was observed in formulations with 20 and 30 wt% of fibre content.

Quantifying the Shape Memory Performance of a Three-Dimensional-Printed Biobased Polyester/Cellulose Composite Material.

A biobased composite material with heat-triggered shape memory ability was successfully formulated for three-dimensional (3D) printing. It was produced from cellulose nanocrystals and cellulose micro-powder particles within a bioderived thermally cured polyester matrix based on glycerol, citric acid, and sebacic acid. The effect of curing duration on the material's shape memory behavior was quantified by using two thermo-mechanical approaches to measure recovery: (1) displacement in three-point bending and (2) angular recovery from a beam bent at 90° in a single cantilever setup.