Nitrogen Incorporation in Potassic and Micro- and Meso-Porous Minerals: Potential Biogeochemical Records and Targets for Mars Sampling.

We measured the N concentrations and isotopic compositions of 44 samples of terrestrial potassic and micro- and meso-porous minerals and a small number of whole-rocks to determine the extent to which N is incorporated and stored during weathering and low-temperature hydrothermal alteration in Mars surface/near-surface environments. The selection of these minerals and other materials was partly guided by the study of altered volcanic glass from Antarctica and Iceland, in which the incorporation of N as NH in phyllosilicates is indicated by correlated concentrations of N and the LILEs (, K, Ba, Rb, Cs), with scatter likely related to the presence of exchanged, occluded/trapped, or encapsulated organic/inorganic N occurring within structural cavities (, in zeolites). The phyllosilicates, zeolites, and sulfates analyzed in this study contain between 0 and 99,120 ppm N and have δN values of -34‰ to +65‰.

Radiometric calibration of thermal emission data from the Asteroid and Lunar Environment Chamber (ALEC).

The vacuum and thermal environment of airless planetary surfaces, particularly those dominated by a particulate regolith such as the Moon and asteroids, produces intense near-surface thermal gradients that can substantially alter their thermal emissivity spectra when compared with spectra collected at ambient terrestrial conditions. Therefore, spectroscopic measurements acquired under conditions designed to simulate the radiation environment in which remote measurements of airless bodies are made should be used as the basis for interpreting those data. As a foundation for this goal, we report the radiometric calibration of thermal infrared emission data collected with a Fourier transform infrared spectrometer integrated with the custom Asteroid and Lunar Environment Chamber (ALEC) at Brown University.

Primordial clays on Mars formed beneath a steam or supercritical atmosphere.

On Mars, clay minerals are widespread in terrains that date back to the Noachian period (4.1 billion to 3.7 billion years ago).

Land-use change affects water recycling in Brazil's last agricultural frontier.

Historically, conservation-oriented research and policy in Brazil have focused on Amazon deforestation, but a majority of Brazil's deforestation and agricultural expansion has occurred in the neighboring Cerrado biome, a biodiversity hotspot comprised of dry forests, woodland savannas, and grasslands. Resilience of rainfed agriculture in both biomes likely depends on water recycling in undisturbed Cerrado vegetation; yet little is known about how changes in land-use and land-cover affect regional climate feedbacks in the Cerrado. We used remote sensing techniques to map land-use change across the Cerrado from 2003 to 2013.

Socioeconomic development and agricultural intensification in Mato Grosso.

The Brazilian agro-industrial frontier in Mato Grosso rapidly expanded in total area of mechanized production and in total value of production in the last decade. This article shows the spatial pattern of that expansion from 2000 to 2010, based on novel analyses of satellite imagery. It then explores quantitatively and qualitatively the antecedents and correlates of intensification, the expansion of the area under two crops per year.

Subsurface water and clay mineral formation during the early history of Mars.

Clay minerals, recently discovered to be widespread in Mars's Noachian terrains, indicate long-duration interaction between water and rock over 3.7 billion years ago. Analysis of how they formed should indicate what environmental conditions prevailed on early Mars.

Historical carbon emissions and uptake from the agricultural frontier of the Brazilian Amazon.

Tropical ecosystems play a large and complex role in the global carbon cycle. Clearing of natural ecosystems for agriculture leads to large pulses of CO2 to the atmosphere from terrestrial biomass. Concurrently, the remaining intact ecosystems, especially tropical forests, may be sequestering a large amount of carbon from the atmosphere in response to global environmental changes including climate changes and an increase in atmospheric CO2.

Greenhouse gas emissions from alternative futures of deforestation and agricultural management in the southern Amazon.

The Brazilian Amazon is one of the most rapidly developing agricultural areas in the world and represents a potentially large future source of greenhouse gases from land clearing and subsequent agricultural management. In an integrated approach, we estimate the greenhouse gas dynamics of natural ecosystems and agricultural ecosystems after clearing in the context of a future climate. We examine scenarios of deforestation and postclearing land use to estimate the future (2006-2050) impacts on carbon dioxide (CO(2)), methane (CH(4)), and nitrous oxide (N(2)O) emissions from the agricultural frontier state of Mato Grosso, using a process-based biogeochemistry model, the Terrestrial Ecosystems Model (TEM).

Key scientific questions and key investigations from the first international conference on Martian phyllosilicates.

Minerals and their occurrences can tell us about the chemistry, pressure, and temperatures of past environments on Mars and thus allow inferences about the potential for habitability. Thanks to recent space exploration, a new vision is emerging wherein Mars hosted environmental conditions of potential astrobiological relevance. This epoch is identified by the presence of phyllosilicate-bearing deposits, which are generally contained in very ancient basement rocks.

Orbital identification of carbonate-bearing rocks on Mars.

Geochemical models for Mars predict carbonate formation during aqueous alteration. Carbonate-bearing rocks had not previously been detected on Mars' surface, but Mars Reconnaissance Orbiter mapping reveals a regional rock layer with near-infrared spectral characteristics that are consistent with the presence of magnesium carbonate in the Nili Fossae region. The carbonate is closely associated with both phyllosilicate-bearing and olivine-rich rock units and probably formed during the Noachian or early Hesperian era from the alteration of olivine by either hydrothermal fluids or near-surface water.

Phyllosilicate diversity and past aqueous activity revealed at Mawrth Vallis, Mars.

Observations by the Mars Reconnaissance Orbiter/Compact Reconnaissance Imaging Spectrometer for Mars in the Mawrth Vallis region show several phyllosilicate species, indicating a wide range of past aqueous activity. Iron/magnesium (Fe/Mg)-smectite is observed in light-toned outcrops that probably formed via aqueous alteration of basalt of the ancient cratered terrain. This unit is overlain by rocks rich in hydrated silica, montmorillonite, and kaolinite that may have formed via subsequent leaching of Fe and Mg through extended aqueous events or a change in aqueous chemistry.

Hydrated silicate minerals on Mars observed by the Mars Reconnaissance Orbiter CRISM instrument.

Phyllosilicates, a class of hydrous mineral first definitively identified on Mars by the OMEGA (Observatoire pour la Mineralogie, L'Eau, les Glaces et l'Activitié) instrument, preserve a record of the interaction of water with rocks on Mars. Global mapping showed that phyllosilicates are widespread but are apparently restricted to ancient terrains and a relatively narrow range of mineralogy (Fe/Mg and Al smectite clays). This was interpreted to indicate that phyllosilicate formation occurred during the Noachian (the earliest geological era of Mars), and that the conditions necessary for phyllosilicate formation (moderate to high pH and high water activity) were specific to surface environments during the earliest era of Mars's history.

Characterizing the landscape dynamics of an invasive plant and risk of invasion using remote sensing.

Improved understanding of the spatial dynamics of invasive plant species may lead to more effective land management and reduced future invasion. Here, we identified the spatial extents of nonnative cheatgrass (Bromus tectorum) in the north central Great Basin using remotely sensed data from Landsat MSS, TM, and ETM+. We compared cheatgrass extents in 1973 and 2001 to six spatially explicit landscape variables: elevation, aspect, hydrographic channels, cultivation, roads, and power lines.

Global mineralogical and aqueous mars history derived from OMEGA/Mars Express data.

Global mineralogical mapping of Mars by the Observatoire pour la Mineralogie, l'Eau, les Glaces et l'Activité (OMEGA) instrument on the European Space Agency's Mars Express spacecraft provides new information on Mars' geological and climatic history. Phyllosilicates formed by aqueous alteration very early in the planet's history (the "phyllocian" era) are found in the oldest terrains; sulfates were formed in a second era (the "theiikian" era) in an acidic environment. Beginning about 3.

Recent ice ages on Mars.

A key pacemaker of ice ages on the Earth is climatic forcing due to variations in planetary orbital parameters. Recent Mars exploration has revealed dusty, water-ice-rich mantling deposits that are layered, metres thick and latitude dependent, occurring in both hemispheres from mid-latitudes to the poles. Here we show evidence that these deposits formed during a geologically recent ice age that occurred from about 2.

Orbital forcing of the martian polar layered deposits.

Since the first images of polar regions on Mars revealed alternating bright and dark layers, there has been speculation that their formation might be tied to the planet's orbital climate forcing. But uncertainties in the deposition timescale exceed two orders of magnitude: estimates based on assumptions of dust deposition, ice formation and sublimation, and their variations with orbital forcing suggest a deposition rate of 10(-3) to 10(-2) cm yr(-1) (refs 5, 6), whereas estimates based on cratering rate result in values as high as 0.1 to 0.