Transport of Potential Manure Hormone and Pharmaceutical Contaminants through Intact Soil Columns.

Although adding manure to agricultural soils is a commonly practiced disposal method and a means to enhance soil productivity, potential environmental contamination by any associated chemicals of emerging concern (CECs) such as hormones and pharmaceuticals is not well understood. Our objective was to provide field-relevant predictions of soil transport and attenuation of 19 potential manure CECs using undisturbed soil columns irrigated under unsaturated conditions. The CEC concentrations in leached water were monitored for 13 wk using high performance liquid chromatography-time of flight-mass spectrometry (HPLC-TOF-MS), after which time soil in the cores was removed and sampled for extractable CECs.