Nanodiamond-Decorated Silica Spheres as a Chromatographic Material.

Nanodiamond (ND) particles (∼5 nm), obtained from detonation soot, were oxidized and/or thermally hydrogenated. Both, the non-hydrogenated and hydrogenated ND particles were successfully coupled to the surface of micrometer-size organo-silica particles. A thin layer of nanodiamonds (NDs) decorating the surface of the organo-silica particles was visible on transmission electron microscopy (TEM) images.

Spectroscopic characteristics of carbon dots (C-dots) derived from carbon fibers and conversion to sulfur-bridged C-dots nanosheets.

We synthesized sub-10 nm carbon nanoparticles (CNPs) consistent with photoluminescent carbon dots (C-dots) from carbon fiber starting material. The production of different C-dots fractions was monitored over seven days. During the course of the reaction, one fraction of C-dots species with relatively high photoluminescence was short-lived, emerging during the first hour of reaction but disappearing after one day of reaction.

Hidden Properties of Carbon Dots Revealed After HPLC Fractionation.

Carbon dots (C-dots) are often synthesized, modified, and studied as a mixture. Unfortunately, the spectroscopic and biological properties measured for such C-dots assume that there is a high degree of homogeneity in the produced sample. By means of high-resolution separation techniques, we show that "as-synthesized" C-dots exist as a relatively complex mixture and that an unprecedented reduction in such complexity can reveal fractions of C-dots with unique luminescence properties.

Fractionation of carbon-based nanomaterials by anion-exchange HPLC.

A sample containing carbon nanoparticles was obtained starting with the soot generated during combustion of inexpensive paraffin oil in a flame. The complexity of the sample, however, required fractionation to isolate its components. Anion-exchange high-performance liquid chromatography (AE-HPLC) was used for the analysis and collection of soot-derived carbon nanoparticles.

Physical characterization and evaluation of HPLC columns packed with superficially porous particles.

Two HPLC columns packed with superficially porous packing material (Kinetex™ 1.7 and 2.6 μm C18 particles) were evaluated in terms of their physical properties and performance characteristics.

Controlling the formation of silver nanoparticles on silica by photochemical deposition and other means.

Silver nanoparticles (Ag-NP) on silica were produced in aqueous solution by deposition of silver on colloidal silica in a small cuvette using radiation from a xenon-mercury lamp. Ag-NP were also synthesized on a much larger scale with low-level, long-term visible light irradiation for several months. In both cases, the nanoparticle production was monitored by the appearance of the surface plasmon resonance (SPR) band at around 410 nm.