Adsorption and transport of arsenic(V) in experimental subsurface systems.

The adsorption and transport of As(V) in a heterogeneous, iron oxide-containing soil was investigated in batch and column laboratory experiments. The As(V) adsorbed rapidly to the soil over the first 48 h, but continued to adsorb slowly over the next several weeks, clearly indicating the potential for rate-limited transport. The equilibrium As(V) adsorption isotherm was markedly nonlinear, further indicating the potential for nonideal transport.

Field Determination of Aquifer Thermal Energy Storage Parameters.

Determination of the potential of a specific confined aquifer as an effective thermal energy storage medium requires thorough knowledge of the geochemical, thermodynamic, and hydraulic properties of the aquifer and its confining layers. A series of laboratory and field studies must be performed in order to determine the fundamental parameters. Procedures and analyses of a series of tests for a confined aquifer near Mobile, Alabama were completed prior to an aquifer thermal energy storage experiment.