Magnetic Coupling in Colloidal Clusters for Hierarchical Self-Assembly.

Manipulating the way in which colloidal particles self-organize is a central challenge in the design of functional soft materials. Meeting this challenge requires the use of building blocks that interact with one another in a highly specific manner. Their fabrication, however, is limited by the complexity of the available synthesis procedures.

Self-assembly of charged colloidal cubes.

In this work, we show how and why the interactions between charged cubic colloids range from radially isotropic to strongly directionally anisotropic, depending on tuneable factors. Using molecular dynamics simulations, we illustrate the effects of typical solvents to complement experimental investigations of cube assembly. We find that in low-salinity water solutions, where cube self-assembly is observed, the colloidal shape anisotropy leads to the strongest attraction along the corner-to-corner line, followed by edge-to-edge, with a face-to-face configuration of the cubes only becoming energetically favorable after the colloids have collapsed into the van der Waals attraction minimum.

Self-organization in dipolar cube fluids constrained by competing anisotropies.

For magnetite spherical nanoparticles, the orientation of the dipole moment in the crystal does not affect the morphology of either zero field or field induced structures. For non-spherical particles however, an interplay between particle shape and direction of the magnetic moment can give rise to unusual behaviors, in particular when the moment is not aligned along a particle symmetry axis. Here we disclose for the first time the unique magnetic properties of hematite cubic particles and show the exact orientation of the cubes' dipole moment.

Nanoparticle Shape Influences the Magnetic Response of Ferro-Colloids.

The interesting magnetic response of conventional ferro-colloid has proved extremely useful in a wide range of technical applications. Furthermore, the use of nano/micro- sized magnetic particles has proliferated cutting-edge medical research, such as drug targeting and hyperthermia. In order to diversify and improve the application of such systems, new avenues of functionality must be explored.

How cube-like must magnetic nanoparticles be to modify their self-assembly?

Systems whose magnetic response can be finely tuned using control parameters, such as temperature and external magnetic field strength, are extremely desirable, functional materials. Magnetic nanoparticles, in particular suspensions thereof, offer opportunities for this controllability to be realised. Cube-like particles are particularly mono-disperse examples that, together with their favourable packing behaviour, make them of significant interest for study.

Directional self-assembly of permanently magnetised nanocubes in quasi two dimensional layers.

To design modern materials with a specific response, the consequences of directionally dependent interactions on the self-assembly of constituent nanoparticles need to be properly understood. Directionality arises in the study of anisometric nanoparticles, where geometry has a drastic effect on the properties observed. Given the fact that magnetic interactions are inherently anisotropic, if one constructs these particles from a magnetic medium, an interesting interplay between the two sources of directionality will occur.