The chemical foaming technique is possibly the most common method of producing porous geopolymers. Despite this, to date, the role of the content and type of surfactant on the pore size distribution of porous geopolymers is not fully perceived, as constant surfactant dosages are usually employed. In addition, the comparison of literature studies is challenging since a distinct mixture of designs is employed.
View Article and Find Full Text PDFIn this work, alkali-activated fly ash-derived foams were produced at room temperature by direct foaming using aluminum powder. The 1 cm foams (cubes) were then evaluated as adsorbents to extract heavy metals from aqueous solutions. The foams' selectivity towards lead, cadmium, zinc, and copper ions was evaluated in single, binary, and multicomponent ionic solutions.
View Article and Find Full Text PDFIn anaerobic digestion processes, pH has a vital role due to the direct impacts on the microbial community. An eco-friendly approach has been applied to control pH in anaerobic bioreactors, using waste-containing fly ash geopolymer spheres (GS) instead of powdered chemical compounds, to promote continuous alkalis leaching. The influence of GS porosity and concentration on the behavior of anaerobic sequential batch reactor treating cheese whey was evaluated.
View Article and Find Full Text PDFRed mud-based inorganic polymer spheres were used as alternative pH regulators and process enhancers in sequencing batch anaerobic reactors treating cheese whey. This byproduct tends to quickly acidify under anaerobic conditions, and the common route to control pH and ensure suitable conditions for methane production involves the use of commercial alkaline raw materials. The spheres were synthesized using significant amounts of hazardous and toxic waste, red mud (50 wt% of solid components), whose recycling is challenging.
View Article and Find Full Text PDFThis work reports a simple and safe, but powerful, route to depollute lead-containing aqueous solutions. Inorganic polymer foams (cm-size) were used as bulk-type adsorbents. The influence of the specimens' porosity and activator molarity on the foams' physical properties and on their lead extraction ability was studied.
View Article and Find Full Text PDFIn this study, and for the first time, red mud (RM)-based geopolymer spheres were synthesised, with varying porosity and RM content, and then their use as pH regulators was evaluated. The aluminosilicate sources of these inorganic polymers were 100% waste-based, consisting of a mixture of RM and fly ash wastes. Geopolymer spheres containing up to 60 wt.
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