Symmetry Breaking in Rationally Designed Copper Oxide Electrocatalyst Boosts the Oxygen Reduction Reaction.

Oxygen reduction reaction (ORR) kinetics is critically dependent on the precise modulation of the interactions between the key oxygen intermediates and catalytic active sites. Herein, a novel electrocatalyst is reported, featuring nitrogen-doped carbon-supported ultra-small copper oxide nanoparticles with the broken-symmetry C coordination filed sites, achieved by a mild γ-ray radiation-induced method. The as-synthesized catalyst exhibits an excellent ORR activity with a half-wave potential of 0.

Cooperative NHC and Photoredox Catalyzed Radical Aminoacylation of Alkenes to Tetrahydropyridazines.

Tetrahydropyridazines constitute an important structural motif found in numerous natural products and pharmaceutical compounds. Herein, we report an aminoacylation reaction of alkenes that enables the synthesis of 1,4,5,6-tetrahydropyridazines through cooperative N-heterocyclic carbene (NHC) and photoredox catalysis. This approach involves the 6-endo-trig cyclization of N-centered hydrazonyl radicals, generated via single-electron oxidation of hydrazones, followed by a radical-radical coupling step.

Advanced Hollow Cubic FeCo-N-C Cathode Electrocatalyst for Ultrahigh-Power Aluminum-Air Battery.

The exploration of electrocatalysts toward oxygen reduction reaction (ORR) is pivotal in the development of diverse batteries and fuel cells that rely on ORR. Here, a FeCo-N-C electrocatalyst (FeCo-HNC) featuring with atomically dispersed dual metal sites (Fe-Co) and hollow cubic structure is reported, which exhibits high activity for electrocatalysis of ORR in alkaline electrolyte, as evidenced by a half-wave potential of 0.907 V, outperforming that of the commercial Pt/C catalyst.

Mechanically Robust and Highly Conductive Poly(ionic liquid)/Polyacrylamide Double-Network Hydrogel Electrolytes for Flexible Symmetric Supercapacitors with a Wide Operating Voltage Range.

Flexible electronic devices, such as supercapacitors (SCs), place high demands on the mechanical properties, ionic conductivity, and electrochemical stability of electrolytes. Hydrogels, which combine flexibility and the advantages of both solid and liquid electrolytes, will meet the demand. Here, we report the synthesis of novel poly(ionic liquid)/polyacrylamide double-network (DN) (PIL/PAM DN) hydrogel electrolytes containing different metal salts via a two-step γ-radiation method.

An Exploration into the Fault Diagnosis of Analog Circuits Using Enhanced Golden Eagle Optimized 1D-Convolutional Neural Network (CNN) with a Time-Frequency Domain Input and Attention Mechanism.

With the continuous operation of analog circuits, the component degradation problem gradually comes to the forefront, which may lead to problems, such as circuit performance degradation, system stability reductions, and signal quality degradation, which could be particularly evident in increasingly complex electronic systems. At the same time, due to factors, such as continuous signal transformation, the fluctuation of component parameters, and the nonlinear characteristics of components, traditional fault localization methods are still facing significant challenges when dealing with large-scale complex circuit faults. Based on this, this paper proposes a fault-diagnosis method for analog circuits using the ECWGEO algorithm, an enhanced version of the GEO algorithm, to de-optimize the 1D-CNN with an attention mechanism to handle time-frequency fusion inputs.

Impacts of projected changes in sea surface temperature on ozone pollution in China toward carbon neutrality.

The global sea surface temperatures (SSTs) are expected to change diversely in the future under different climate scenarios, which will affect the near-surface ozone (O) distribution and concentration by influencing meteorological states and large-scale atmospheric circulation. Many countries have planned to reach carbon neutrality by the mid-21st century. In this study, the impacts of global and regional SST changes on near-surface O concentrations in China in the middle of the 21st century under the carbon-neutral scenario (Shared Socioeconomic Pathway 1-1.

A pH-responsive polymer linked with immunomodulatory drugs: synthesis, characteristics and in vitro biocompatibility.

Cancer immunotherapy is a promising method for cancer therapy. Imiquimod (R837) is a molecule that could activate immune systems for cancer immunotherapy, but an easily manufactured biocompatible carrier to deliver R837 may be needed to overcome the disadvantages of R837. Micelles formed by biocompatible copolymers have been widely used to deliver chemotherapeutic drugs but not immunotherapeutic drugs.