Interfacial engineering-based colonization of biofilms on polyethylene terephthalate (PET) surfaces: Implications for whole-cell biodegradation of microplastics.

Microplastic pollution has become a significant environmental issue. One of the most important sources and components of microplastics is polyester fabric - polyethylene terephthalate (PET). Because the catalytic depolymerization of PET typically requires specific conditions such as alkaline environments, specific solvents, or high temperatures, there is an urgent need for a simpler, eco-friendly solution with high degradation efficiency for managing the vast amounts of PET textile waste.

A wearable sensor based on janus fabric upon an electrochemical analysis platform for sweat glucose detection.

Wearable sweat sensing devices have drawn much attention due to their noninvasive and portable properties, which is emerging as a promising technology in daily healthiness assessment issues. A sweat sensor based on Janus fabric and electrochemical analysis is proposed in this work. Unidirectional moisture transported behavior of the Janus fabric serves as the quick-drying component directly contacting skin to transfer sweat toward the detection site.

A sensor platform based on SERS detection/janus textile for sweat glucose and lactate analysis toward portable monitoring of wellness status.

Herein we report a wearable sweat sensor of a Janus fabric based on surface enhanced Raman scattering (SERS) technology, mainly detecting the two important metabolites glucose and lactate. Janus fabric is composed of electrospinning PU on a piece of medical gauze (cotton), working as the unidirectional moisture transport component (R = 1305%) to collect and transfer sweat efficiently. SERS tags with different structures act as the probe to recognize and detect the glucose and lactate in high sensitivity.

Cu/Co Bimetallic Carbon Catalyst as a Highly Efficient Promoter for Reactive Dyes Degradation with PMS.

The synergistic effect between bimetallic catalysts has been confirmed as an effective method for activating persulfate (PMS). Therefore, we immobilized copper-cobalt on chitosan to prepare bimetallic carbon catalysts for PMS activation and degradation of reactive dyes. Experimental results demonstrate that the CuCo-CTs/PMS catalytic degradation system exhibits excellent degradation performance toward various types of reactive dyes (e.

Instant mucus dressing of PEO reinforced by chitosan nanofiber scaffold for open wound healing.

Dressings seamlessly attached to the open wound bed are necessary for fully unleashing the dressing healing ability, as leaving the voids beneath the dressing poses infection hazards. The present study prepared an instant mucus dressing (IMD) of polyethylene oxide (PEO) reinforced by chitosan (CS) nanofiber scaffold, which formed by immersing PEO/CS nanofiber mat in water. The PEO/CS nanofiber mat were fabricated by the solution blow spinning (SBS) method using PEO and CS mixed solutions.

Novel multifunctional environmentally friendly degradable zeolitic imidazolate frameworks@poly (γ-glutamic acid) hydrogel with efficient dye adsorption function.

Recently, metal-organic frameworks (MOFs) have been widely developed due to the rich porosity, excellent framework structure and multifunctional nature. Meanwhile, a series of MOFs crystals and MOF-based composites have been emerged. However, the widespread applications of MOFs are hindered by challenges such as rigidity, fragility, solution instability, and processing difficulties.

In Situ Generated UiO-66/Cotton Fabric Easily Recyclable for Reactive Dye Adsorption.

In view of the environmental pollution caused by the widespread use of reactive dyes in the printing and dyeing industry, the modified cotton fabric was loaded with the extremely stable metal-organic frame (MOF) material UiO-66 for removing reactive dyes from colored wastewater. UiO-66/cotton fabric was prepared by in situ synthesis, and its surface morphology and structure were analyzed by XRD, SEM, BET, and XPS. The adsorption performance of UiO-66/cotton fabric on reactive dyes was investigated by adsorbent dosage, adsorption time and temperature, dye concentration, pH, and so on.

Washable Patches with Gold Nanowires/Textiles in Wearable Sensors for Health Monitoring.

Textile-based flexible electronic devices have attracted tremendous attention in wearable sensors due to their excellent skin affinity and conformability. However, the washing process of such devices may damage the electronic components. Here, a textile-based piezoresistive sensor with ultrahigh sensitivity was fabricated through the layered integration of gold nanowire (AuNW)-impregnated cotton fabric and silver ink screen-printed nylon fabric electrodes, sealing with Parafilm.

Improvement of biodegradation of PET microplastics with whole-cell biocatalyst by interface activation reinforcement.

Polyethylene terephthalate (PET) is an important basic polymer, which was used widely in variety of fields. Due to its high crystallinity, compact structure and strong surface hydrophobicity, PET has prominent resistance to biodegradation. In recent years, microplastics, especially polyethylene terephthalate (PET) microplastics, was considered as serious threaten to ecosystems.

Bio-based poly (γ-glutamic acid)-gelatin double-network hydrogel with high strength for wound healing.

Building bio-based hydrogels with high strength and biocompatibility is still a challenge. Herein, we successfully constructed a hybrid double-network (DN) full biological hydrogel with excellent mechanical properties and biocompatibility by introducing a physically cross-linked gelatin (GEL) network in a covalently cross-linked poly (γ-glutamic acid) (γ-PGA) network. The γ-PGA-GEL DN hydrogel demonstrated ultra-high compression performance (38 MPa), which was better than all currently reported γ-PGA-based hydrogels, and its tensile performance (0.

A thread/fabric-based band as a flexible and wearable microfluidic device for sweat sensing and monitoring.

Flexible biosensors for monitoring systems have emerged as a promising portable diagnostics platform due to their potential for in situ point-of-care (POC) analytic devices. Assessment of biological analytes in sweat can provide essential information for human physiology. Conventional measurements rely on laboratory equipment.

Bio-based poly (γ-glutamic acid) hydrogels reinforced with bacterial cellulose nanofibers exhibiting superior mechanical properties and cytocompatibility.

Natural polymer hydrogels are expected to be promising biomaterial because of its excellent biocompatibility and biodegradability, but they are soft and easily broken. Herein, the poly (γ-glutamic acid) (γ-PGA)/bacterial cellulose (BC) composite hydrogels with excellent mechanical properties were constructed by introducing bacterial cellulose. The γ-PGA/BC composite hydrogels were obtained by the covalent cross-linking of γ-PGA in the BC nanofibers suspensions.

Nitrogen, Phosphorus and Sulfur Co-Doped Pyrolyzed Bacterial Cellulose Nanofibers for Supercapacitors.

Heteroatom doping is an effective way to raise the electrochemical properties of carbon materials. In this paper, a novel electrode material including nitrogen, phosphorus, and sulfur co-doped pyrolyzed bacterial cellulose (N/P/S-PBC) nanofibers was produced. The morphologies, structure characteristics and electrochemical performances of the materials were investigated by Scanning electron microscopy, Fourier transform infrared spectra, X-ray diffraction patterns, X-ray photoelectronic spectroscopy, N sorption analysis and electrochemical measurements.

A poly(allylamine hydrochloride)/poly(styrene sulfonate) microcapsule-coated cotton fabric for stimulus-responsive textiles.

This study reports the design of a stimulus-responsive fabric incorporating a combination of microcapsules, containing polyelectrolytes poly(allylamine hydrochloride) (PAH) and poly(styrene sulfonate) sodium salt (PSS), formed a layer-by-layer (LBL) approach. The use of PAH and PSS ensured that the microcapsule structure was robust and pH-sensitive. SEM and TEM studies showed that the composite microcapsule (PAH/PSS) PAH had a spherical morphology with a hollow structure.

Design and Optimization of Flexible Polypyrrole/Bacterial Cellulose Conductive Nanocomposites Using Response Surface Methodology.

Flexible conductive materials have greatly promoted the rapid development of intelligent and wearable textiles. This article reports the design of flexible polypyrrole/bacterial cellulose (PPy/BC) conductive nanocomposites by in situ chemical polymerization. Box-Behnken response surface methodology has been applied to optimize the process.

Biodegradation of Microplastic Derived from Poly(ethylene terephthalate) with Bacterial Whole-Cell Biocatalysts.

At present, the pollution of microplastic directly threatens ecology, food safety and even human health. Polyethylene terephthalate (PET) is one of the most common of microplastics. In this study, the micro-size PET particles were employed as analog of microplastic.

Bio-Preparation and Regulation of Pyrrole Structure Nano-Pigment Based on Biomimetic Membrane.

Microbial pigments, regarded as the most potential biomass pigments, have lately attracted increasing attention in textile dyeing due to their sustainability and cleaner production. The pyrrole structure microbial pigment, called prodigiosin, recently have become a research hotspot for its bright colors and antibacterial function. However, in most case the extraction and preparation are time-consuming and expensive processes since these kinds of microbial pigments are intracellular metabolites.

Biomedical Potential of Ultrafine Ag Nanoparticles Coated on Poly (Gamma-Glutamic Acid) Hydrogel with Special Reference to Wound Healing.

In wound care management, the prevention of wound infection and the retention of an appropriate level of moisture are two major challenges. Therefore, designing an excellent antibacterial hydrogel with a suitable water-adsorbing capacity is very important to improve the development of wound dressings. In this paper, a novel silver nanoparticles/poly (gamma-glutamic acid) (γ-PGA) composite dressing was prepared for biomedical applications.

Preparation of Biocolorant and Eco-Dyeing Derived from Polyphenols Based on Laccase-Catalyzed Oxidative Polymerization.

Natural products have been believed to be a promising source to obtain ecological dyes and pigments. Plant polyphenol is a kind of significant natural compound, and tea provides a rich source of polyphenols. In this study, biocolorant derived from phenolic compounds was generated based on laccase-catalyzed oxidative polymerization, and eco-dyeing of silk and wool fabrics with pigments derived from tea was investigated under the influence of pH variation.

Eco-dyeing with biocolourant based on natural compounds.

Biomass pigments have been regarded as promising alternatives to conventional synthetic dyestuffs for the development of sustainable and clean dyeing. This investigation focused on dyeing of fabrics with biopigments derived from tea polyphenols via non-enzymatic browning reaction. The average particle size of dyed residual liquor with natural tea polyphenol was 717.

Novel Biological Hydrogel: Swelling Behaviors Study in Salt Solutions with Different Ionic Valence Number.

In this paper, poly γ-glutamic acid/ε-polylysine (γ-PGA/ε-PL) hydrogels were successful prepared. The γ-PGA/ε-PL hydrogels could be used to remove Na⁺, Ca, and Cr from aqueous solution and were characterized by scanning electron microscopy. The performance of hydrogels were estimated under different ionic concentration, temperature, and pH.

pH-Mediated Antibacterial Dyeing of Cotton with Prodigiosins Nanomicelles Produced by Microbial Fermentation.

This study developed a novel pH-mediated antimicrobial dyeing process of cotton with prodigiosins nanomicelles produced by microbial fermentation. The average diameter of the pigment nanomicelles was 223.8 nm (range of 92.

Preparation and properties of EDC/NHS mediated crosslinking poly (gamma-glutamic acid)/epsilon-polylysine hydrogels.

In this paper, a novel pH-sensitive poly (amino acid) hydrogel based on poly γ-glutamic acid (γ-PGA) and ε-polylysine (ε-PL) was prepared by carbodiimide (EDC) and N-hydroxysuccinimide (NHS) mediated polymerization. The influence of PGA/PL molar ratio and EDC/NHS concentration on the structure and properties was studied. Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) proved that hydrogels were crosslinked through amide bond linkage, and the conversion rate of a carboxyl group could reach 96%.

Application of terahertz time-domain spectroscopy in intracellular metabolite detection.

Using terahertz time-domain spectroscopy (THz-TDS), we have investigated the THz spectra of astaxanthin and riboflavin and the spectra of two kinds of cell, haenatcoccus plusivalis and bacillus subtilis, which could produce astaxanthin and riboflavin, respectively, during their metabolite process. Riboflavin was found to be much more absorptive to THz radiation and have richer spectral characteristics than astaxanthin. As an intracellular metabolite, riboflavin could be distinguished from the cells by using THz-TDS.