Leaching of per- and polyfluoroalkyl substances (PFAS) from municipal solid waste incineration bottom ash intended for utilization as secondary aggregates in road subbase.

Ten samples of mineral fraction derived from waste incineration bottom ash (MIBA) from Denmark (N = 7), Sweden (N = 1), and the Czech Republic (N = 2) underwent targeted analysis of 59 per- and polyfluoroalkyl substances (PFAS) in the solid phase and eluates from a batch leaching test at a liquid-to-solid ratio of 2 L/kg. The solid content, expressed as ΣPFAS, ranged from 0.21 ± 0.

What waste management can learn from the traditional mining sector: Towards an integrated assessment and reporting of anthropogenic resources.

Many organizations in Europe collect data and perform research on municipal solid waste and the secondary raw materials that can be produced from them through recycling, urban mining, or landfill mining. However, the information generated and presented thereby is often highly aggregated, while research activities are many a time isolated. Both reduce the usability of the data and information generated.

Legal situation and current practice of waste incineration bottom ash utilisation in Europe.

Almost 500 municipal solid waste incineration plants in the EU, Norway and Switzerland generate about 17.6 Mt/a of incinerator bottom ash (IBA). IBA contains minerals and metals.

Optimizing large-scale ageing of municipal solid waste incinerator bottom ash prior to the advanced metal recovery: Phase I: Monitoring of temperature, moisture content, and CO level.

Development of temperature, CO level, and moisture was followed during several months of outdoor ageing of municipal solid waste incineration bottom ash (IBA) in seventeen 5000-ton piles, in order to obtain input data for possible optimization of the ageing process in terms of faster/better drying prior to the metal recovery operation. In addition, measured thermal conductivity and specific heat capacity of IBA were combined with calculated thermal output and used as input to a model originally developed for accessing temperature development in hardening concrete structures. The results show that the temperature in pile's core increased to 90-94 °C in two-three weeks and remained stable for at least another month.

Leaching behaviour of incineration bottom ash in a reuse scenario: 12years-field data vs. lab test results.

Several types of standardized laboratory leaching tests have been developed during the past few decades to evaluate the leaching behaviour of waste materials as a function of different parameters, such as the pH of the eluate and the liquid to solid ratio. However, the link between the results of these tests and leaching data collected from the field (e.g.

Construction and demolition waste: Comparison of standard up-flow column and down-flow lysimeter leaching tests.

Five samples of construction and demolition waste (C&DW) were investigated in order to quantify leaching of inorganic elements under percolation conditions according to two different experimental setups: standardised up-flow saturated columns (<4mm particle size) and unsaturated, intermittent down-flow lysimeters (<40mm particle size). While standardised column tests are meant primarily to provide basic information on characteristic leaching properties and mechanisms and not to reproduce field conditions, the lysimeters were intended to mimic the actual leaching conditions when C&DW is used in unbound geotechnical layers. In practice, results from standardised percolation tests are often interpreted as estimations of actual release from solid materials in percolation scenarios.

Leaching from waste incineration bottom ashes treated in a rotary kiln.

Leaching from municipal solid waste incineration bottom ash treated in a rotary kiln was quantified using a combination of lab-scale leaching experiments and geochemical modelling. Thermal treatment in the rotary kiln had no significant effect on the leaching of Al, Ba, Ca, Mg, Si, Sr, Zn, sulfate and inorganic carbon. Leaching of these elements from the treated residues remained unchanged and was, in general, controlled by solubility of the same minerals as in the untreated residues.

Life-cycle assessment of selected management options for air pollution control residues from waste incineration.

Based on available technology and emission data seven selected management options for air-pollution-control (APC) residues from waste incineration were evaluated by life-cycle assessment (LCA) using the EASEWASTE model. Scenarios were evaluated with respect to both non-toxicity impact categories (e.g.

Influence of operational conditions, waste input and ageing on contaminant leaching from waste incinerator bottom ash: a full-scale study.

Leaching of metals and Cl from fresh, naturally aged, and lab-scale aged bottom ashes generated during full-scale incineration experiments with different operational conditions (OC) and waste input (WI) was assessed. Although significant differences in the bulk contents of the generated bottom ashes were observed between the individual experiments, addition of 5.5 wt.

Effect of drying on leaching testing of treated municipal solid waste incineration APC-residues.

Air-pollution-control (APC) residues from waste incinerators are hazardous waste according to European legislation and must be treated prior to landfilling. Batch and column leaching data determine which type of landfill can receive the treated APC-residues. CEN standards are prescribed for the batch and column leaching test; however, these standards do not specify whether or not the residue samples should be dried prior to the leaching testing.

Leaching from MSWI bottom ash: evaluation of non-equilibrium in column percolation experiments.

Impacts of non-equilibrium on results of percolation experiments on municipal solid waste incineration (MSWI) bottom ash were investigated. Three parallel column experiments were performed: two columns with undisturbed percolation and one column with two sets of 1-month-long flow interruptions applied at liquid-to-solid (L/S) ratios of L/S 2L/kg and 12L/kg, respectively. Concentrations of Na, K, Cl(-), Ca, Si, SO(4)(2-), Al, Cu, Ni, Mo, Ba, Pb, Zn, and dissolved organic carbon (DOC) were monitored throughout the entire leaching period; geochemical modeling was used to identify non-equilibrium-induced changes in the solubility control.

Long-term leaching from MSWI air-pollution-control residues: leaching characterization and modeling.

Long-term leaching of Ca, Fe, Mg, K, Na, S, Al, As, Ba, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Zn, Mo, Sb, Si, Sn, Sr, Ti, V, P, Cl, and dissolved organic carbon from two different municipal solid waste incineration (MSWI) air-pollution-control residues was monitored during 24 months of column percolation experiments; liquid-to-solid (L/S) ratios of 200-250L/kg corresponding to more than 10,000 years in a conventional landfill were reached. Less than 2% of the initially present As, Cu, Pb, Zn, Cr, and Sb had leached during the course of the experiments. Concentrations of Cd, Fe, Mg, Hg, Mn, Ni, Co, Sn, Ti, and P were generally bellow 1microg/L; overall less than 1% of their mass leached.

Influence of test conditions on solubility controlled leaching predictions from air-pollution-control residues.

Leaching of Al, Ca, Mg, Si, S, Ba, Sr, Mo, Zn, Cd, Pb, and Cu from waste incineration air-pollution-control (APC) residues was investigated. Real-life conditions, i.e.