In Situ Electrodeposition of Ultralow Pt into NiFe-Metal-Organic Framework/Nickel Foam Nanosheet Arrays as a Bifunctional Catalyst for Overall Water Splitting.

Exploring highly effective bifunctional electrocatalysts with surface structural advantages and synergistic optimization effects among multimetals is greatly important for overall water splitting. Herein, we successfully synthesized Pt-loaded NiFe-metal-organic framework nanosheet arrays grown on nickel foam (Pt-NiFe-MOF/NF) via a facile hydrothermal-electrodeposition process. Benefiting from large exposed specific surface, optimal electrical conductivity and efficient metal-support interaction endow Pt-NiFe-MOF/NF with highly catalytic performance, exhibiting small overpotential of 261 mV toward oxygen evolution reaction and 125 mV toward hydrogen evolution reaction at a current density of 100 mA cm in alkaline medium.

Ir-Doped Bilayer Heterojunction Hollow Nanoboxes for Electrocatalytic Oxygen Evolution.

The fabrication of hollow nanoelectrocatalysts with multilayered heterogeneous interfaces, derived from metal-organic framework (MOF) materials, represents a highly efficient strategy that promotes the oxygen evolution reaction (OER). Within this research, we successfully synthesized a hollow nanobox of Ir-doped ZIF-67@CoFe PBA with bilayer heterointerfaces. The distinctive structure of Ir-ZIF-67@CoFe PBA provides a substantial number of active sites for reaction intermediates, resulting in improved utilization of precious metals.

Nanosheet-assembled transition metal sulfides nanoflowers derived from CoMo-MOF for efficient oxygen evolution reaction.

Oxygen evolution reaction (OER) is a multi-electron transfer process, whose intrinsic sluggish dynamic restricts the whole process of overall water splitting (OWS). To address this issue, a porous transition metal sulfide (TMS) catalyst with rich heterojunctions was prepared by vulcanization and trace Fe doping of CoMo-based metal-organic framework (MOF). In this work, the nanoflower composed of ultrathin 2D nanosheets anchored on a nickel foam presents a layered interface that contributes to the exposure of active regions.

Heterostructure engineering and ultralow Pt-loaded multicomponent nanocage for efficient electrocatalytic oxygen evolution.

Developing highly efficient electrocatalysts based on appropriate heterojunction engineering and electronic structure modification for the oxygen evolution reaction (OER) has been extensively recognized as an effective approach to increase the efficiency of water splitting. Herein, ultralow Pt-loaded (1 %) NiCoFeP@NiCoFe-PBA hollow nanocages with well-defined heterointerfaces and modified electronic environment are successfully fabricated. As expected, the obtained Pt-NiCoFeP@NiCoFe-PBA exhibits outstanding performance with a low overpotential of 255 mV at 10 mA cm and a small Tafel slope of 57.

phosphoselenization induced heterointerface engineering endow NiSe/NiP/FeSe hollow nanocages with efficient water oxidation electrocatalysis performance.

Exploiting Earth-abundant and highly effective electrocatalysts toward the oxygen evolution reaction (OER) is critical for boosting water splitting efficiency. Herein, we proposed a novel phosphoselenization strategy to fabricate heterostructured NiSe/NiP/FeSe (NiFePSe) nanocages with a modified electronic structure and well-defined nanointerfaces. Owing to the strong interfacial coupling and synergistic effect among the three components, the prepared NiFePSe nanocages exhibit superior OER performance with an ultralow overpotential of 242 mV at 10 mA cm and a small Tafel slope of 55.

Self-Reconstruction of Fe-Doped Co-Metal-Organic Frameworks Boosted Electrocatalytic Performance for Oxygen Evolution Reaction.

Rational design of facile and low-cost efficient electrocatalysts for oxygen evolution reaction (OER) is crucial to solve the energy crisis. Benefiting from in situ self-reconstruction from metal-organic frameworks (MOFs) to (oxy)hydroxides in alkaline electrolytes, MOFs have become alternative OER catalysts. Thus, Fe-doped Co-MOF nanosheets (Co-MOF/Fe) were prepared and utilized straightforwardly as OER electrocatalysts.