Solvent Chemistry Manipulated Iodine Redox Thermodynamics For Durable Iodine Batteries.

The diverse valences of iodine enable it with multi-electron transfer capability for energy dense batteries. However, previous studies indicate that the primary I/I redox couple exhibits distinct behaviors depending on electrolyte choice, with the mechanistic basis of aqueous versus nonaqueous systems remaining unclear. Here, we elucidated the solvent effect on iodine redox, particularly focusing on polyiodide formation and their molecular interaction correlations.

Optimizing optical neural network design for enhanced compatibility with analog computation.

This paper breaks away from traditional approaches that merely emulate digital neural networks. Using Mach-Zehnder interferometer (MZI) networks as a case study, we explore the impact of the inherent properties of analog computation on performance and identify the characteristics that optical neural networks (ONNs) components should possess to better adapt to these specific properties. Specifically, we examine the influence of analog computation on bias power and activation functions, as well as the impact of optical pruning on ONN's performance.

Combining citrus waste-derived function microbes with biochar promotes humus formation by enhancing lignocellulose degradation in citrus waste compost.

The low degradation rate of lignocellulose limits the humification process of citrus organic waste composting. This study explored the roles of general microbial inoculation (GM), citrus waste-derived function microbial inoculation (CM), and CM combined with biochar (CMB) in citrus waste compost. Results showed microbial inoculations all promoted lignocellulose degradation and humus formation, but the roles of CM and CMB were better than GM, especially CMB.

High Efficiency Alkaline Iodine Batteries with Multi-Electron Transfer Enabled by Bi/BiO Redox Mediator.

The multi-electron transfer I/IO redox couple is attractive for high energy aqueous batteries. Shifting from an acidic to an alkaline electrolyte significantly enhances the IO formation kinetics due to the spontaneous disproportionation reaction, while the alkaline environment also offers more favorable Zn anode compatibility. However, sluggish kinetics during the reduction of IO persists in both acidic and alkaline electrolytes, compromising the energy efficiency of this glorious redox couple.

Characteristics of Rhizosphere Microbiome, Soil Chemical Properties, and Plant Biomass and Nutrients in cv. Shatangju Exposed to Increasing Soil Cu Levels.

The prolonged utilization of copper (Cu)-containing fungicides results in Cu accumulation and affects soil ecological health. Thus, a pot experiment was conducted using cv. Shatangju with five Cu levels (38, 108, 178, 318, and 388 mg kg) to evaluate the impacts of the soil microbial processes, chemistry properties, and citrus growth.

Research on characteristics and influencing factors of road dust emission in a southern city in China.

One of the primary causes of urban atmospheric particulate matter, which is harmful to human health in addition to affecting air quality and atmospheric visibility, is road dust. This study used online monitoring equipment to examine the characteristics of road dust emissions, the effects of temperature, humidity, and wind speed on road dust, as well as the correlation between road and high-space particulate matter concentrations. A section of a real road in Jinhua City, South China, was chosen for the study.

Energetic Hypervalent Organoiodine Electrochemistry for Aqueous Zinc Batteries.

Hypervalent organoiodine compounds have been extensively utilized in organic synthesis, yet their electrochemical properties remain unexplored despite their theoretically high redox potential compared with inorganic iodine, which primarily relies on the I/I redox couple in battery applications. Here, the fundamental redox mechanism of hypervalent organoiodine in a ZnCl aqueous electrolyte is established for the first time using the simplest iodobenzene (PhI) as a model compound. We validated that the PhI to PhICl transition is a single-step and reversible reaction, enabling two-electron transfer of I/I redox chemistry (1.

Butadiene Sulfone Based Binary Deep Eutectic Electrolyte for High Performance Lithium Metal Batteries.

Deep eutectic electrolytes (DEEs) have attracted significant interest due to the unique physiochemical properties, yet challenges persist in achieving satisfactory Li anode compatibility through a binary DEE formula. In this study, we introduce a nonflammable binary DEE electrolyte comprising of lithium bis(trifluoro-methane-sulfonyl)imide (LiTFSI) and solid butadiene sulfone (BdS), which demonstrates enhanced Li metal compatibility while exhibiting high Li ion migration number (0.52), ionic conductivity (1.

Can carbon emissions trading policy promote product bargaining power increases for high-carbon enterprises? Evidence from China.

Carbon emissions trading policies play a crucial role in facilitating the transition to high-end products within high-carbon enterprises. Nevertheless, current empirical analyses of the carbon emissions trading market exhibit a lack of precision and are susceptible to bias in their findings. Limited research has been conducted on the influence of product quality as a potential constraint on the impact of carbon trading on product bargaining power.

Aqueous Electrolyte With Weak Hydrogen Bonds for Four-Electron Zinc-Iodine Battery Operates in a Wide Temperature Range.

In the pursuit of high-performance energy storage systems, four-electron zinc-iodine aqueous batteries (4eZIBs) with successive I/I/I redox couples are appealing for their potential to deliver high energy density and resource abundance. However, susceptibility of positive valence I to hydrolysis and instability of Zn plating/stripping in conventional aqueous electrolyte pose significant challenges. In response, polyethylene glycol (PEG 200) is introduced as co-solvent in 2 m ZnCl aqueous solution to design a wide temperature electrolyte.

Ruthenium-Catalyzed Difunctionalization of Vinyl Cyclopropanes for Double -C(sp)-H/C-5(sp)-H Functionalization.

With in-depth research on 1,2-difunctionalization, remote difunctionalization has garnered widespread attention for achieving multifunctionality. Herein, we report a strategy for achieving remote difunctionalization under mild conditions. This strategy exhibited good substrate suitability and functional group tolerance.

Machine-Learning-Assisted Instantaneous Frequency Measurement Method Based on Thin-Film Lithium Niobate on an Insulator Phase Modulator for Radar Detection.

A simple microwave photonic, reconfigurable, instantaneous frequency measurement system based on low-voltage thin-film lithium niobate on an insulator phase modulator is put forward and experimentally demonstrated. Changing the wavelength of the optical carrier can realize the flexibility of the frequency measurement range and accuracy, showing that during the ranges of 0-10 GHz, 3-15 GHz, and 12-18 GHz, the average measurement errors are 26.9 MHz, 44.

Integrated self-injection-locked narrow linewidth laser based on thin-film lithium niobate.

Narrow linewidth lasers have a wide range of applications in the fields of coherent optical communications, atomic clocks, and measurement. Lithium niobate material possesses excellent electro-optic and thermo-optic properties, making it an ideal photonic integration platform for a new generation. The light source is a crucial element in large-scale photonic integration.

Correlation of endolymphatic hydrops and perilymphatic enhancement with the clinical features of Ménière's disease.

Objectives: To use three-dimensional real inversion recovery (3D-real IR) MRI to investigate correlations between endolymphatic hydrops (EH) grades or the degree of perilymphatic enhancement (PE) and clinical features of Ménière's disease (MD), as previous findings have been inconsistent.

Methods: A total of 273 consecutive patients with definite unilateral MD were retrospectively enrolled from September 2020 to October 2021. All patients underwent 3D-real IR and 3D-T2WI 6 h after intravenous gadolinium injection.

Constructing a Topologically Adaptable Solid Electrolyte Interphase for a Highly Reversible Zinc Anode.

The performance of aqueous zinc metal batteries is significantly compromised by the stability of the solid electrolyte interphase (SEI), which is intimately linked to the structure of the electrical double layer (EDL) between the zinc anode and electrolyte. Furthermore, understanding the mechanical behavior of SEI is crucial, as it governs its response to stress induced by volume changes, fracture, or deformation. In this study, we introduce l-glutamine (Gln) as an additive to regulate the adsorbed environment of the EDL and in situ produce a hybrid SEI consisting of ZnS and Gln-related species.

MRI can help differentiate Ménière's disease from other menieriform diseases.

It is difficult to distinguish other pathologies mimicking Ménière's disease (MD) clinically. This study aims to investigate the differences of imaging findings and features between MD and other menieriform diseases via intravenous gadolinium-enhanced magnetic resonance imaging (MRI). 426 patients with menieriform symptoms, including MD, vestibular migraine (VM), and vestibular schwannoma (VS), underwent 3D-FLAIR and 3D-T2WI MRI 6 h after the intravenous gadolinium injection.

Stereoselective Synthesis of Multisubstituted Alkenes via Ruthenium-Catalyzed Remote Migration Arylation of Nonactivated Olefins.

Polysubstituted alkenes are an important class of organic intermediates that widely exist in various natural products and drug molecules. Herein, we reported a stereoselective synthesis of multisubstituted alkenes via ruthenium-catalyzed remote migration arylation of nonactivated olefins. This strategy exhibited wide substrate suitability and excellent functional group tolerance.

Improving diagnostic accuracy for probable and definite Ménière's disease using magnetic resonance imaging.

Purpose: To determine whether magnetic resonance imaging (MRI) can improve diagnostic accuracy for definite and probable Ménière's disease (MD) based on perilymphatic enhancement (PE) and endolymphatic hydrops (EH).

Methods: 363 patients with unilateral MD (probable MD, n = 75 and definite MD, n = 288) were recruited. A three-dimensional zoomed imaging technique with parallel transmission SPACE real inversion recovery was performed 6 h after intravenous gadolinium injection to investigate the presence of PE and to evaluate the grading and location of EH.

Ultrahigh-Q lithium niobate microring resonator with multimode waveguide.

Difficulty in etching lithium niobate (LN) results in a relatively high propagation loss, which necessitates sophisticated processes to fabricate high-quality factor (Q) microresonators. Here, we fabricate a multimode microring resonator with an intrinsic Q of 6 × 10, which exhibits a propagation loss 50 times lower than that of a single-mode LN microring fabricated under the same process. Notably, the excitation of higher-order modes in the multimode microring is effectively suppressed by utilizing the Euler bend.

Unravelling rechargeable zinc-copper batteries by a chloride shuttle in a biphasic electrolyte.

The zinc-copper redox couple exhibits several merits, which motivated us to reconstruct the rechargeable Daniell cell by combining chloride shuttle chemistry in a zinc chloride-based aqueous/organic biphasic electrolyte. An ion-selective interface was established to restrict the copper ions in the aqueous phase while ensuring chloride transfer. We demonstrated that the copper-water-chloro solvation complexes are the descriptors, which are predominant in aqueous solutions with optimized concentrations of zinc chloride; thus, copper crossover is prevented.

Role of T2 mapping of magnetic resonance imaging in the differentiation of endometrial cancer and benign endometrial lesions.

Purpose: The T2 mapping of magnetic resonance imaging (MRI) in endometrial cancer (EC), benign endometrial lesions (BELs), and normal endometrium (NE) has rarely been reported. This study aimed to determine the T2 values of MRI in EC, BELs, and NE to investigate whether the T2 values can differentiate them and to assess the aggressiveness of EC.

Methods: In total, 73 patients [EC, 51 (age, 57.

Longitudinal variation of endolymphatic hydrops in patients with Ménière's disease.

Background: The relationships of endolymphatic hydrops (EH) and perilymphatic enhancement (PE) with Ménière's disease (MD) remains unclear. This study aimed to describe the dynamic variation of EH and PE for MD patients over 2 hospitalizations by applying magnetic resonance imaging (MRI) to further clarify the relationships of EH and PE with MD.

Methods: A total of 77 MD patients who underwent inner ear MRI after intravenous administration of gadolinium and pure-tone average (PTA) testing during a first and second hospitalization were included.

Chloroplast gene expression level is negatively correlated with evolutionary rates and selective pressure while positively with codon usage bias in Ophioglossum vulgatum L.

Background: Characterization of the key factors determining gene expression level has been of significant interest. Previous studies on the relationship among evolutionary rates, codon usage bias, and expression level mostly focused on either nuclear genes or unicellular/multicellular organisms but few in chloroplast (cp) genes. Ophioglossum vulgatum is a unique fern and has important scientific and medicinal values.

Hepatic steatosis with mass effect: A case report.

Background: Hepatic steatosis is a common radiologic finding. Some imaging inklings are the absence of a mass effect, and there is currently no report of hepatic steatosis with mass effect.

Case Summary: A 23-year-old female was admitted due to a liver mass for half a month.

Simple microwave photonic downconversion channelizer based on multi-wavelength laser sources.

This work presents a simple microwave photonic downconversion channelizer based on multi-wavelength laser sources. The design of two laser diode (LD) arrays enables signal multiplexing and simultaneous multichannel downconversion processing, which provide stable, relatively flat, and strong multi-frequency combs. A proof-of-concept experiment was taken, showing that 14.