Based on the ISAM module in the WRF-CMAQ model, this study analyzed the source contribution(both regional and sectoral) of O and its precursors(NO and VOCs) in Zibo in June 2021. Days with a maximum daily 8-h average(MDA8) O higher(lower) than 160 μg·m were defined as polluted(clean) days. Differences in the source contribution between clean days and polluted days were compared, and a typical pollution period was selected for further process analysis.
View Article and Find Full Text PDFThe chlorine radical (Cl) plays a crucial role in the formation of secondary air pollutants by determining the total atmospheric oxidative capacity (AOC). However, there are still large discrepancies among studies on chlorine chemistry, mainly due to uncertainties from three aspects: (a) Anthropogenic emissions of reactive chlorine species from disinfectant usage are typically overlooked. (b) The heterogeneous reaction uptake coefficients used in air quality models resulted in certain differences.
View Article and Find Full Text PDFThe relationship between O and its precursors during urban polluted episodes remains unclear. In this study, the simultaneous source apportionment of VOCs, NO, and O over the Yangtze River Delta (YRD) region during the O polluted episode on July 24-30, 2018, was performed based on the Integrated Source Apportionment Method (ISAM) embedded in the Community Multiscale Air Quality Modeling System (CMAQ). The results of the ISAM were compared with those of the Brute Force Method (BFM) and Positive Matrix Factorization (PMF).
View Article and Find Full Text PDFThe emission and environmental impact of condensable particulate matter (CPM) from coal-fired power plants (CFPPs) are of increasing concern worldwide. Many studies on the characteristics of CPM emission have been conducted in China, but its source profile remains unclear, and its emission inventory remains high uncertainty. In this work, the latest measurements reported in the latest 33 studies for CPM inorganic and organic species emitted from CFPPs in China were summarized, and then a compositional source profile of CPM for CFPPs was developed for the first time in China, which involved 10 inorganic species and 71 organic species.
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