Impact of biochar colloids on thallium(I) transport in water-saturated porous media: Effects of pH and ionic strength.

Understanding the migration behavior of thallium (TI) in subsurface environments is essential for Tl pollution prevention. With the wide production and utilization of biochar, the notable ability of biochar colloids to carry environmental contaminants may make these colloids important for Tl(I) mobility. This study systematically investigated the impact of wood-derived biochar (WB) and corn straw-derived biochar (CB) colloids on Tl(I) transport in water-saturated porous media under different pH (5, 7 and 10) and ionic strengths (ISs) (1, 5 and 50 mM NaNO).

Retention of thallium(I) on goethite, hematite, and manganite: Quantitative insights and mechanistic study.

The reversibility of monovalent thallium (Tl) absorption on widely distributed iron/manganese secondary minerals may affect environmental Tl migration and global cycling. Nevertheless, quantitative and mechanistic studies on the interfacial retention and release reactions involving Tl(I) are limited. In this study, batch and stirred-flow experiments, unified kinetics modeling, spectral detection, and theoretical calculations were used to elucidate the retention behaviors of Tl(I) on goethite, hematite, and manganite with different solution pH values and Tl loading concentrations.

Thermodynamic and kinetic coupling modeling for thallium(I) sorption at a heterogeneous titanium dioxide interface.

The transformations of monovalent thallium (Tl) in an aqueous environment may be affected significantly by Tl(I) partitioning at the solid-water interface during sorption. Models used to quantify the kinetics of Tl(I) adsorption on heterogeneous adsorbents and formation of multiple complexes under a wide range of water chemistry conditions can accurately predict the environmental fate of thallium. In this study, Tl(I) sorption on representative titanium dioxide at different solution pH values and loading concentrations was investigated with two unified adsorption models, diffuse layer modeling and kinetics modeling.

Cotransport of thallium(I) with polystyrene plastic particles in water-saturated porous media.

Exploring the transport behaviors of thallium (Tl) in porous media is crucial for predicting Tl pollution in natural soils and groundwater. In recent years, the misuse of plastics has led to plastic becoming an emerging pollutant in soil. In this work, the effects of plastic particles on Tl(I) transport in water-saturated sand columns were investigated under different ionic strengths (ISs), pH values, and plastic particle sizes.

A critical review on sulfur reduction of aqueous selenite: Mechanisms and applications.

Selenite, which is extremely toxic at high concentrations, can easily be enriched in natural aquatic environments due to human activities, which causes great harm to ecosystems. Sulfur reduction can effectively reduce soluble selenite in large quantities to nontoxic solid elemental selenium, which plays a significant role in controlling the toxicity and cycle of selenium. In view of the bright prospects of the sulfur reduction reaction of selenite, this review comprehensively summarizes the continuous development in the sulfidation of selenite.

Transport of Tl(I) in water-saturated porous media: Role of carbonate, phosphate and macromolecular organic matter.

Understanding the transport behaviors of thallium (Tl) in porous media is of considerable interest for both natural soils and artificial filtration removal of Tl. In this context, the transport behaviors of Tl(I) in water-saturated sand columns under different conditions were systematically investigated. It was found that, in addition to the effects of pH and ionic strength (IS), the transport of Tl(I) depended on the carbonate, phosphate and macromolecular organic matter as well.

Thallium(I) Oxidation by Permanganate and Chlorine: Kinetics and Manganese Dioxide Catalysis.

The oxidation of the toxic heavy metal thallium(I) (Tl(I)) is an efficient way to enhance Tl removal from water and wastewater. However, few studies have focused on the kinetics of Tl(I) oxidation in water, especially at environmentally relevant pH values. Therefore, the kinetics and mechanisms of Tl(I) oxidation by the common agents KMnO and HOCl under environmentally relevant pH condition were explored in the present study.