Publications by authors named "Jinkui Zhao"

Manipulating the polarization of spin current is essential for understanding the mechanism of charge-to-spin conversion and achieving efficient electrically driven magnetization switching. Here, a novel exchange-spring magnetic structure is introduced formed by the coupling of perpendicular magnetic anisotropy (PMA) CoTb and in-plane magnetic anisotropy (IMA) Co films. When a spin current with the polarization along the y-direction flows through this exchange-spring (x-z plane) structure, the interaction between the y-spin and the local exchange field with a non-collinear spatial distribution gives rise to substantial unconventional spin polarizations in the x- and z-directions, enabling field-free spin-orbit torque driven perpendicular magnetization switching at room temperature.

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  • The research focuses on a newly discovered family of Rare Earth (RE)-based spin ladder compounds, BaREGeO (RE = Pr, Nd, Gd-Ho), which contrasts with the more commonly studied transition metal-based compounds.
  • These compounds have a unique two-leg spin ladder structure with strong interactions facilitated by RE-O connections, making them significant for studying spin dynamics.
  • Notably, BaDyGeO exhibits interesting low-temperature behaviors, including a spin-dimerized state and antiferromagnetic order, highlighting the potential for exploring unique magnetic and quantum properties in 4f electron systems.
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  • Bilayer and trilayer nickelate superconductors, specifically LaNiO (n=2 and 3), show unique properties at both high-temperature superconductivity and ambient pressure, including non-Fermi liquid behavior and density-wave transitions.
  • Using ultrafast reflectivity measurements, researchers found significant differences in the dynamics of bilayer and trilayer nickelates, highlighting a coherent phonon mode in the bilayer LaNiO that isn’t present in the trilayer.
  • The study reveals that the electron-phonon coupling has a minor effect on the electronic properties of LaNiO, with findings necessary for further understanding the relationship between superconductivity and density-wave transitions in these materials.*
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  • Anionic redox chemistry improves energy density in oxide cathodes, but often causes oxygen release which destabilizes their structure.!* -
  • This study introduces a new crystal structure design that successfully prevents oxygen release, validated by various advanced techniques including electrochemical mass spectrometry and electron paramagnetic resonance.!* -
  • The resulting sodium manganese-based oxide shows excellent performance with a reversible capacity of 247 mA h/g and 91.4% capacity retention after 300 cycles, while maintaining structural integrity during cycling.!*
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High-voltage ultrahigh-Ni cathodes (LiNiCoMnO, x≥0.9) can significantly enhance the energy density and cost-effectiveness of Li-ion batteries beyond current levels. However, severe Li-Ni antisite defects and their undetermined dynamic evolutions during high-voltage cycling limit the further development of these ultrahigh-Ni cathodes.

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  • - The study focuses on improving nitric oxide (NO) detection methods by using a surface-scattering sensing strategy that provides specific molecular detection, overcoming limitations of rapid detection techniques.
  • - A new gas sensor is developed using two-dimensional BiOSe in a Schottky junction, achieving quick response times (under 200 seconds) and high sensitivity (up to 16.8 %·ppb) for NO, outperforming typical breath gas sensors.
  • - The sensor uses multiple response signals, including resistance and impedance angle, which are analyzed through principal component analysis to differentiate between various gases, linking molecular characteristics to changes in dipole moments of the target gas.
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Increasing the charging cutoff voltage is a viable approach to push the energy density limits of LiCoO and meet the requirements of the rapid development of 3C electronics. However, an irreversible oxygen redox is readily triggered by the high charging voltage, which severely restricts practical applications of high-voltage LiCoO. In this study, we propose a modification strategy via suppressing surface ligand-to-metal charge transfer to inhibit the oxygen redox-induced structure instability.

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All-Mn-based Li-rich cathodes Li MnO have attracted extensive attention because of their cost advantage and ultrahigh theoretical capacity. However, the unstable anionic redox reaction (ARR), which involves irreversible oxygen releases, causes declines in cycling capacity and intercalation potential, thus hindering their practical applications. Here, it is proposed that introducing stacking-fault defects into the Li MnO can localize oxygen lattice evolutions and stabilize the ARR, eliminating oxygen releases.

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  • - The study investigates gas sensors that detect volatile organic compounds (VOCs) in human breath, specifically aiming to identify the disease marker acetone at very low concentrations (parts per trillion).
  • - It utilizes a Schottky junction gas-sensing strategy, which allows for precise detection of acetone by measuring the reactance signal related to different adsorbate dopings.
  • - The developed sensing method offers rapid detection (around 100 seconds), operates at room temperature, and achieves a detection limit of 34 ppt, demonstrating its potential for identifying health conditions via breath analysis.
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  • * The study highlights a significant interaction between l-OR and structural changes, affecting the electrochemical properties of these materials.
  • * Using advanced neutron scattering techniques, the research identifies local transition metal migration and nanopore formation linked to l-OR, explaining how these phenomena contribute to voltage instability and reduced battery performance over time.
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  • Monoclinic LiCoSbO has been studied as a potential candidate for a Kitaev spin liquid, while the magnetic properties of its less-explored orthorhombic phase have been investigated using various techniques like magnetic susceptibility, muon spin relaxation, and neutron diffraction.
  • The study observes multiple magnetic transitions occurring at temperatures of 115, 89, and 71 K, with higher external magnetic fields suppressing these transitions below 115 K.
  • Zero-field ac susceptibility measurements reveal additional transitions around 114, 107, 97, 79, and 71 K, and specific techniques confirm a long-range magnetic ordered state at roughly 115 K, with discrepancies attributed to stacking faults and local disarray
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Exponential function is a basic form of temporal signals, and how to fast acquire this signal is one of the fundamental problems and frontiers in signal processing. To achieve this goal, partial data may be acquired but result in severe artifacts in its spectrum, which is the Fourier transform of exponentials. Thus, reliable spectrum reconstruction is highly expected in the fast data acquisition in many applications, such as chemistry, biology, and medical imaging.

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By using temperature-dependent neutron powder diffraction combined with maximum entropy method analysis, a previously unreported Li lattice site was discovered in the argyrodite LiPSCl solid-state electrolyte. This new finding enables a more complete description of the Li diffusion model in argyrodites, providing structural guidance for designing novel high-conductivity solid-state electrolytes.

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Dynamic nuclear polarization (DNP) can provide a powerful means to amplify neutron diffraction from biological crystals by 10-100-fold, while simultaneously enhancing the visibility of hydrogen by an order of magnitude. Polarizing the neutron beam and aligning the proton spins in a polarized sample modulates the coherent and incoherent neutron scattering cross-sections of hydrogen, in ideal cases amplifying the coherent scattering by almost an order of magnitude and suppressing the incoherent background to zero. This chapter describes current efforts to develop and apply DNP techniques for spin polarized neutron protein crystallography, highlighting concepts, experimental design, labeling strategies and recent results, as well as considering new strategies for data collection and analysis that these techniques could enable.

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The present study was carried out with the surface electromyography signal of subjects during the time when subjects did the exercises of the 6 core stability trainings. We analyzed the different activity level of surface electromyography signal, and finally got various fatigue states of muscles in different exercises. Thirty subjects completed exercises of 6 core stability trainings, which were prone bridge, supine bridge, unilateral bridge (divided into two trainings, the left and right sides alternatively) and bird-dog (divided into two trainings, the left and right sides alternatively), respectively.

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Ezrin is a member of the ezrin-radixin-moesin family (ERM) of adapter proteins that are localized at the interface between the cell membrane and the cortical actin cytoskeleton, and they regulate a variety of cellular functions. The structure representing a dormant and closed conformation of an ERM protein has previously been determined by x-ray crystallography. Here, using contrast variation small angle neutron scattering, we reveal the structural changes of the full-length ezrin upon binding to the signaling lipid phosphatidylinositol 4,5-bisphosphate (PIP(2)) and to F-actin.

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