Publications by authors named "Jinjun Cai"

The bacterial community performs an essential ecological role in maintaining agriculture systems. The roles of bacteria in the forest, marine, and agricultural systems have been studied extensively and intensively. However, similar studies in the areas irrigated by the Yellow River remain limited.

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It is of great significance for the conservation of biodiversity in farmland ecosystems to study the diversity, structure, functions, and biogeographical distribution of soil microbes in farmland and their influencing factors. High-throughput sequencing technology was used to analyze the distribution characteristics of soil bacterial diversity, community structure, and metabolic function along elevation and their responses to soil physicochemical properties in farmland in the loess hilly areas of Ningxia. The results showed that:â‘  The Alpha diversity index of soil bacterial was significantly negatively correlated with elevation ( < 0.

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The construction of heterojunctions and surface defects is a promising strategy for enhancing photocatalytic activity. A surface sulfur vacancy (V)-rich ZnInS/BiMoO heterojunction photocatalyst (ZIS-V/BMO) was herein developed for the selective oxidation of biomass-derived 5-hydroxymethyl furfural (HMF) to value-added 2,5-diformylfuran (DFF) coupled with H production. The ZIS-V/BMO heterojunction consisted of BiMoO (BMO) with preferentially exposed high-index (131) facets and V-rich two-dimensional (2D) ZnInS (ZIS-V) nanosheets with preferentially exposed high-index (102) facets.

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Biochar is known to efficiently remove dyes especially for biochar with hierarchical pores and partial N-species. Here, a facile pyrolysis is used to yield N-doped biochar from kelp without additives, showing surface areas of 771 m/g as temperature up to 1000 °C and hierarchical small-sized mesopores (2-4 nm) and wide meso-macropores (8-60 nm). A possible self-template mechanism from inorganics is proposed to form hierarchical pore architecture in biochar and used for methylene blue (MB) removal.

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Salt stress is a major abiotic stress affecting plant growth and crop yield. For the successful cultivation of alfalfa ( L.), a key legume forage, in saline-affected areas, it's essential to explore genetic modifications to improve salt-tolerance.

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Article Synopsis
  • The study developed ACB-BiWO and ACB-BiMoO composites using activated biochar to enhance their adsorption and photocatalytic performance for degrading pollutants like rhodamine B, tetracycline, and norfloxacin.
  • The ACB-BiWO composite showed the most effective removal rates for these substances, attributed to its better photogenerated carrier management and absorption characteristics.
  • The research concluded that ACB-BiWO is highly effective for wastewater treatment and disinfection, showcasing its potential for environmental applications with excellent reusability and sterilization capabilities.
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To improve the performance of graphitic carbon nitride (g-CN), a hotly researched metal-free photocatalyst, for better application in the efficient removal of organic pollutants, adsorption synergistically enhanced photocatalysis mechanism was thoroughly explored. Based on KOH pore-forming activated biochar (ACB) and K doped g-CN (K-gCN), the novel activated biochar-based K-gCN composite (ACB-K-gCN) was synthesized via the innovative ultrasonic-milling method. Rhodamine B (RhB), tetracycline (TC), norfloxacin (NOR), and chloramphenicol (CAP) were selected as target pollutants, and the effects of environmental factors, recycling and actual wastewater tests, disinfection effects, and various enhancement strategies were investigated.

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MiR156/s (s) module is the key regulatory hub of juvenile-to-adult phase transition as a critical flowering regulator. In this study, a miR156-targeted was identified and characterized in switchgrass ( L.), a dual-purpose fodder and biofuel crop.

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The adsorption treatment of ammonium-containing wastewater has attracted significant global attention. Most enhanced adsorption methods employ chemical modification, and there are few reports on physical activation. We present a physical activation to explore whether physical ultrasound may enhance the adsorption performance and comprehensive utilisation of a new forestry waste, Caragana korshinskii was used as a feedstock to prepare activated biochar (ACB) by controlling the pyrolysis temperatures and ultrasound parameters.

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Biomass is a promising carbon source because of its low-cost and rich carbon component. Here, lotus root as self N-source was used to produce N-doped biochar via a simple carbonization after freeze-drying, showing surface areas up to 694 m/g with partial mesopores. Applicability of biochar as adsorbent for dyes removal was explored using methyl orange (MO) as model pollutant dye.

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N-doped carbons were obtained from bamboo shoot shell via hydrothermal pretreatment under salt assistance followed by carbonization, using melamine as nitrogen source. The carbons with tubular morphology and surface areas in 406-489 m/g range were used as adsorbents for the removal of methyl orange (MO) and rhodamine B (RhB). Adsorption isotherms and kinetic fitting showed much better accordance with Freundlich model and pseudo-second-order, showing balanced capacity (q) of 50 mg/g for MO and 42 mg/g for RhB on the pristine carbons (BHC-800) at 25 °C.

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Metal-organic frameworks (MOFs) have emerged as promising materials in the areas of gas storage, magnetism, luminescence, and catalysis owing to their superior property of having highly crystalline structures. However, MOF stability toward heat or humidity is considerably less as compared to carbons because they are constructed from the assembly of ligands with metal ions or clusters via coordination bonds. Transforming MOFs into carbons is bringing the novel potential for MOFs to achieve industrialization, and carbons with controlled pore sizes and surface doping are one of the most important porous materials.

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A new microwave catalytic oxidation process based on two kinds of catalysts, the commercially available activated carbon (AC) and Mn2O3 nanoparticle modified AC (Mn2O3/AC), was reported for the degradation of 4-nitrophenol (4-NP) without adding any oxidant. Effects of microwave power, catalyst dosage, irradiation time, and initial concentration for the degradation efficiency were studied. Results indicated that catalyst of Mn2O3/AC showed much higher catalytic activity than pure AC and Mn2O3 particles.

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The quantum sieving effect of H2/D2 at 77 K on commercially available carbon molecular sieves (1.5GN-H and 3KT-172) was studied. An exceptional reverse kinetic quantum effect is observed on 1.

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Poly(vinylidene chloride)-based carbon (PC) with ultrahigh microporisity was prepared by simple carbonization and KOH activation, exhibiting great potential to be superior CO2, CH4, and H2 adsorbent at high pressures. The CO2 uptake for pristine PC is highly up to 3.97 mmol/g at 25 °C and 1 bar while the activated PC exhibits a slightly lower uptake at 1 bar.

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The microporous coordination polymer [Co(H2 L)(bipy)0.5 ]⋅2 H2 O (1, bipy=4,4'-bipyridine) was synthesized on the basis of the V-shaped flexible diphosphonate ligand (2,4,6-trimethyl-1,3-phenylene)bis(methylene)diphosphonic acid (H4 L) and the auxiliary bipy ligand under hydrothermal conditions. The structure of this compound was characterized by single-crystal X-ray diffraction.

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We report the preparation of ordered porous carbons for the first time via nanocasting zeolite 10X with an aim to evaluate their potential application for hydrogen storage. The synthesized carbons exhibit large Brunauer-Emmett-Teller surface areas in the 1300-3331 m(2)/g range and pore volumes up to 1.94 cm(3)/g with a pore size centered at 1.

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A 3D porous aluminum(III) trisphosphonate, constructed from 1D inorganic aluminum phosphate chains and tripodal organic linkers, contains large hexagonal channels (1.24 nm in diameter) and a highly accessible void (50.3%) which allow it to have a fast and relatively high uptake of H2, N2 and CO2.

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