Solution Sequential Deposition Pseudo-Planar Heterojunction: An Efficient Strategy for State-of-Art Organic Solar Cells.

Organic solar cells (OSCs) are considered as a promising new generation of clean energy. Bulk heterojunction (BHJ) structure has been widely employed in the active layer of efficient OSCs. However, precise regulation of morphology in BHJ is still challenging due to the competitive coupling between crystallization and phase separation.

Dual Function of the Third Component in Ternary Organic Solar Cells: Broaden the Spectrum and Optimize the Morphology.

Ternary organic solar cells (T-OSCs) have attracted significant attention as high-performance devices. In recent years, T-OSCs have achieved remarkable progress with power conversion efficiency (PCE) exceeding 19%. However, the introduction of the third component complicates the intermolecular interaction compared to the binary blend, resulting in poor controllability of active layer and limiting performance improvement.

Sensitive photodetection below silicon bandgap using quinoid-capped organic semiconductors.

High-sensitivity organic photodetectors (OPDs) with strong near-infrared (NIR) photoresponse have attracted enormous attention due to potential applications in emerging technologies. However, few organic semiconductors have been reported with photoelectric response beyond ~1.1 μm, the detection limit of silicon detectors.

High performance polymerized small molecule acceptor by synergistic optimization on π-bridge linker and side chain.

The polymerized small-molecule acceptors have attracted great attention for application as polymer acceptor in all-polymer solar cells recently. The modification of small molecule acceptor building block and the π-bridge linker is an effective strategy to improve the photovoltaic performance of the polymer acceptors. In this work, we synthesized a new polymer acceptor PG-IT2F which is a modification of the representative polymer acceptor PY-IT by replacing its upper linear alkyl side chains on the small molecule building block with branched alkyl chains and attaching difluorene substituents on its thiophene π-bridge linker.

A Cathode Interface Layer Based on 4,5,9,10-Pyrene Diimide for Highly Efficient Binary Organic Solar Cells.

Efficient cathode interfacial layers (CILs) are becoming essential elements for organic solar cells (OSCs). However, the absorption of commonly used cathode interfacial materials (CIMs) is either too weak or overlaps too much with that of photoactive materials, hindering their contribution to the light absorption. In this work, we demonstrate the construction of highly efficient CIMs based on 2,7-di-tert-butyl-4,5,9,10-pyrene diimide (t-PyDI) framework.

The Importance of Nonequilibrium to Equilibrium Transition Pathways for the Efficiency and Stability of Organic Solar Cells.

Controlled morphology of solution-processed thin films have realized impressive achievements for non-fullerene acceptor (NFA)-based organic solar cells (OSCs). Given the large set of donor-acceptor pairs, employing various processing conditions to realize optimal morphology for high efficiency and stable OSCs is a strenuous task. Therefore, comprehensive correlations between processing conditions and morphology evolution pathways have to be developed for efficient performance and stability of devices.

Polymerized Small Molecular Acceptor with Branched Side Chains for All Polymer Solar Cells with Efficiency over 16.7.

The power conversion efficiencies (PCEs) of small molecule acceptor (SMA)-based organic solar cells have already exceeded 18%. However, the development of polymer acceptors still lags far behind their SMA counterparts mainly due to the lack of efficient polymer acceptors. Herein, a series of polymer acceptors named PY-X (with X being the branched alkyl chain) are designed and synthesized by employing the same central core with the SMA L8-BO but with different branched alkyl chains on the pyrrole motif.

Different Morphology Dependence for Efficient Indoor Organic Photovoltaics: The Role of the Leakage Current and Recombination Losses.

Efficient indoor organic photovoltaics (OPVs) have attracted strong attention for their application in indoor electronic devices. However, the route to optimal photoactive film morphology toward high-performance indoor devices has remained obscure. The leakage current dominated by morphology exerts distinguishing influence on the performance under different illuminations.

Intermolecular Interaction Control Enables Co-optimization of Efficiency, Deformability, Mechanical and Thermal Stability of Stretchable Organic Solar Cells.

Promoting efficiency, deformability, and life expectancy of stretchable organic solar cells (OSCs) have always been key concerns that researchers are committed to solving. However, how to improve them simultaneously remains challenging, as morphology parameters, such as ordered molecular arrangement, beneficial for highly efficient devices actually limits mechanical stability and deformability. In this study, the unfavorable trade-off among these properties has been reconciled in an all-polymer model system utilizing a mechanically deformable guest component.

High-Performance Fluorinated Fused-Ring Electron Acceptor with 3D Stacking and Exciton/Charge Transport.

A new fluorinated electron acceptor (FINIC) based on 6,6,12,12-tetrakis(3-fluoro-4-hexylphenyl)-indacenobis(dithieno[3,2-b;2',3'-d]thiophene) as the electron-donating central core and 5,6-difluoro-3-(1,1-dicyanomethylene)-1-indanone as the electron-deficient end groups is rationally designed and synthesized. FINIC shows similar absorption profile in dilute solution to the nonfluorinated analogue INIC. However, compared with INIC, FINIC film shows red-shifted absorption, down-shifted frontier molecular orbital energy levels, enhanced crystallinity, and more ordered molecular packing.

Balancing Crystal Size in Small-Molecule Nonfullerene Solar Cells through Fine-Tuning the Film-Forming Kinetics to Fabricate Interpenetrating Network.

The nanoscale interpenetrating network of active layer plays a key role in determining the exciton dissociation and charge transport in all small-molecule nonfullerene solar cells (AS-NFSCs). However, fabricating interpenetrating networks in all small-molecule blends remains a critical hurdle due to the uncontrolled crystallization behavior of small molecules. In this study, we proposed that the balanced crystal size between the donor and the acceptor is an essential prerequisite to construct optimal interpenetrating networks.

14.7% Efficiency Organic Photovoltaic Cells Enabled by Active Materials with a Large Electrostatic Potential Difference.

Although significant improvements have been achieved for organic photovoltaic cells (OPVs), the top-performing devices still show power conversion efficiencies far behind those of commercialized solar cells. One of the main reasons is the large driving force required for separating electron-hole pairs. Here, we demonstrate an efficiency of 14.

13%-Efficiency Quaternary Polymer Solar Cell with Nonfullerene and Fullerene as Mixed Electron Acceptor Materials.

In this article, we report 13%-efficiency quaternary polymer solar cell. By introducing bis-PCBM:PCBM into a known nonfullerene system-poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl))benzo[1,2- b:4,5- b']dithiophene)- co-(1,3-di(5-thiophene-2-yl)-5,7-bis(2-ethylhexyl)benzo[1,2- c:4,5- c']dithiophene-4,8-dione):3,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone-methyl))-5,5,11,11-tetrakis(4- n-hexylphenyl)-dithieno[2,3 d:2',3' d']- s-indaceno[1,2 b:5,6 b']dithiophene (PBDB-T:IT-M), the quaternary solar cell significantly outperforms the nonfullerene binary and the ternary (PBDB-T:IT-M:fullerene) devices with a significant increase in the short-circuit current-density (18.2 vs 16.

Achieving Balanced Crystallinity of Donor and Acceptor by Combining Blade-Coating and Ternary Strategies in Organic Solar Cells.

As a prototype tool for slot-die coating, blade-coating exhibits excellent compatibility with large-area roll-to-roll coating. A ternary organic solar cell based on PBDB-T:PTB7-Th:FOIC blends is fabricated by blade-coating and exhibits a power conversion efficiency of 12.02%, which is one of the highest values for the printed organic solar cells in ambient environment.

High-Performance Ternary Organic Solar Cell Enabled by a Thick Active Layer Containing a Liquid Crystalline Small Molecule Donor.

Ternary organic solar cells (OSCs) have attracted much research attention in the past few years, as ternary organic blends can broaden the absorption range of OSCs without the use of complicated tandem cell structures. Despite their broadened absorption range, the light harvesting capability of ternary OSCs is still limited because most ternary OSCs use thin active layers of about 100 nm in thickness, which is not sufficient to absorb all photons in their spectral range and may also cause problems for future roll-to-roll mass production that requires thick active layers. In this paper, we report a highly efficient ternary OSC (11.