Stereodefined vinylboron compounds are important organic synthons. The synthesis of E-1-vinylboron compounds typically involves the addition of a B-H bond to terminal alkynes. The selective generation of the thermodynamically unfavorable Z-isomers remains challenging, necessitating improved methods.
View Article and Find Full Text PDFEfficient degradation of plastics, the vital challenge for a sustainable future, stands in need of better chemical recycling procedures that help produce commercially valuable small molecules and redefine plastic waste as a rich source of chemical feedstock. However, the corresponding chemical recycling methods, while being generally restricted to polar polymers, need improvement. Particularly, degradation of chemically inert nonpolar polymers, the major constitutes of plastics, suffers from low selectivity and very harsh transformation conditions.
View Article and Find Full Text PDFThe analysis of mycotoxins in foodstuffs is affected by the complexity of the matrix and the extremely low concentration levels. The development of sample pretreatment and analytical methods that enable highly selective enrichment as well as highly sensitive detection is of great significance for food safety. This paper reviews the recent progress in biotoxin analysis methods and summarizes the prospects and development of this field.
View Article and Find Full Text PDF