Strategy for predicting catalytic activity of catalysts with hierarchical nanostructures.

Three-dimensional hierarchical nanostructures have been employed as electrodes of solid oxide fuel cells (SOFCs) to notably improve the catalytic performance. Hierarchical nanoscale porous electrodes face a trade-off: macroscale pores enhance mass transfer but reduce the number of active sites, while microscale pores increase the number of active sites at the cost of higher transport resistance. Careful design of these structures is crucial for balancing mass transfer and reaction dynamics.