Fluorescent difference between two rhodamine-PAHs polystyrene solid-phase sensors for Hg(II) detection based on crystal structure and density functional theory calculation.

Two novel rhodamine-polystyrene solid-phase fluorescence sensors PS-RB-2 and PS-R6G-2 with pyrene or naphthalene as fluorophore were synthesized for Hg(II) detection. Their structures were characterized by Fourier transform infrared (FTIR) spectra and scanning electron micrographs (SEM). Sensor PS-RB-2 displayed higher selectivity and sensitivity to Hg(II), with a lower detection limit of 0.