Smoking is among the significant adverse factors to reproductive health and accounts for damage to spermatogenesis and maturation of spermatozoa. The proposed research contributes to understanding the potential of to prevent the cytotoxic effect of tobacco smoke on different aspects of male reproductive health, including sperm: sperm morphology, sperm count, testes' weight, luteinizing hormone (LH) and follicle-stimulating hormone (FSH), testosterone, and lipid profile in passive smokers. The experiment on how leaves affect sperm morphology and concentration is performed by grinding leaves to make the aqueous juice.
View Article and Find Full Text PDFThis study introduces a novel system of solid electrolytes for electrical double-layer capacitors (EDLCs) utilizing biopolymer electrolytes with high energy density comparable to NiMH batteries. To prepare the electrolytes, a proton-conducting plasticized chitosan: poly(2-oxazoline) (POZ) with good film-forming properties was fabricated using a solution casting technique, and ammonium trifluoromethanesulfonate (NHCFSO) salt was employed as a proton provider. Various glycerol concentrations were incorporated into the chitosan:POZ: NHCFSO system to enhance the ionic conductivity and fully transparent films were obtained.
View Article and Find Full Text PDFBackground Zinc plays a crucial role in human nutrition and various biochemical processes, making it indispensable for all life forms. Therefore, it is important to address low zinc levels, particularly among women, to prevent potential health issues. Objective This study aimed to evaluate the serum zinc levels of female patients in Sulaymaniyah, Iraq.
View Article and Find Full Text PDFUnlabelled: Despite being very infectious and fatal, the coronavirus disease 2019 (COVID-19) lacks a reliable and practical biomarker to assess how serious it will be.
Aim: The current study aims to conclude the possibility of C-reactive protein (CRP) level serving as a biomarker for early prediction of COVID-19 infections.
Methods: In this retrospective cross-sectional study, 88 people participated who were infected with COVID-19, aged from 25 to 79 years old.
Background: Acute respiratory failure develops quickly in patients with a severe form of coronavirus disease (COVID-19), caused by the severe acute respiratory syndrome Coronavirus 2 (SARS‑CoV‑2). Despite being commonly acknowledged as a measure of the body's overall iron storage, ferritin's predictive value is associated with COVID-19.
Objective: This study aimed to evaluate the relationship between COVID-19 and serum ferritin levels as the biochemical markers of SARS-CoV-2 infection in Sulaymaniyah, Iraq.
Food safety issue is becoming an international challenge for human health owing to the presence of contaminants. In this context, reliable, rapid, and sensitive detecting technology is extremely demanded to establish food safety assurance systems. MOFs (Metal-organic frameworks) are a new type of porous crystalline material with particular physical and chemical characteristics presented in food safety requirements.
View Article and Find Full Text PDFBackground: Coronaviruses (COV) are a large family of viruses that cause infections ranging from the common cold to more serious diseases. Mild to severe respiratory illnesses have been linked to coronavirus disease 2019 (COVID-19), which has been classified as a pandemic disease by the World Health Organization. It has been demonstrated that the severity of COVID-19 is highly positively linked with hypocalcemia.
View Article and Find Full Text PDFThe attention to a stable and ionic conductive electrolyte is driven by the limitations of liquid electrolytes, particularly evaporation and leakage, which restrain their widespread use for electrochemical device applications. Solid polymer electrolyte (SPE) is considered to be a potential alternative since it possesses high safety compared to its counterparts. However, it still suffers from low device efficiency due to an incomplete understanding of the mechanism of ion transport parameters.
View Article and Find Full Text PDFA facile methodology system for synthesizing solid polymer electrolytes (SPEs) based on methylcellulose, dextran, lithium perchlorate (as ionic sources), and glycerol (such as a plasticizer) (MC:Dex:LiClO:Glycerol) has been implemented. Fourier transform infrared spectroscopy (FTIR) and two imperative electrochemical techniques, including linear sweep voltammetry (LSV) and electrical impedance spectroscopy (EIS), were performed on the films to analyze their structural and electrical properties. The FTIR spectra verify the interactions between the electrolyte components.
View Article and Find Full Text PDFStable and ionic conducting electrolytes are needed to make supercapacitors more feasible, because liquid electrolytes have leakage problems and easily undergo solvent evaporation. Polymer-based electrolytes meet the criteria, yet they lack good efficiency due to limited segmental motion. Since metal complexes have crosslinking centers that can be coordinated with the polymer segments, they are regarded as an adequate method to improve the performance of the polymer-based electrolytes.
View Article and Find Full Text PDFFor the first time, biocompatible and biodegradable Ta-metal organic framework (MOF)/polyether block amide (PEBA) fibrous polymeric nanostructures were synthesized by ultrasonic and electrospinning routes in this study. The XRD peaks of products were wider, which is due to the significant effect of the ultrasonic and electrospinning methods on the final product. The adsorption/desorption behavior of the nanostructures is similar to that of the third type of isotherm series, which showed mesoporous behavior for the products.
View Article and Find Full Text PDFIn the present article, a simple technique is provided for the fabrication of a polymer electrolyte system composed of polyvinyl chloride (PVC) and doped with varying content of ammonium iodide (NHI) salt using solution-casting methodology. The influences of NHI on the structural, electrochemical, and electrical properties of PVC have been investigated using X-ray diffraction, electrochemical impedance spectroscopy (EIS), and dielectric properties. The X-ray study reveals the amorphous nature of the polymer-salt complex.
View Article and Find Full Text PDFThis work presents the fabrication of polymer electrolyte membranes (PEMs) that are made of polyvinyl alcohol-methylcellulose (PVA-MC) doped with various amounts of ammonium iodide (NHI). The structural and electrical properties of the polymer blend electrolyte were performed via the acquisition of Fourier Transform Infrared (FTIR) and electrical impedance spectroscopy (EIS), respectively. The interaction among the components of the electrolyte was confirmed via the FTIR approach.
View Article and Find Full Text PDFIn this research, a biopolymer-based electrolyte system involving methylcellulose (MC) as a host polymeric material and potassium iodide (KI) salt as the ionic source was prepared by solution cast technique. The electrolyte with the highest conductivity was used for device application of electrochemical double-layer capacitor (EDLC) with high specific capacitance. The electrical, structural, and electrochemical characteristics of the electrolyte systems were investigated using various techniques.
View Article and Find Full Text PDFIn this work, a green approach was implemented to prepare polymer composites using polyvinyl alcohol polymer and the extract of black tea leaves (polyphenols) in a complex form with Co ions. A range of techniques was used to characterize the Co complex and polymer composite, such as Ultraviolet-visible (UV-Visible) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The optical parameters of absorption edge, refractive index (), dielectric properties including real and imaginary parts (, and ) were also investigated.
View Article and Find Full Text PDFPoly (vinyl alcohol) (PVA)-based solid polymer electrolytes doped with ammonium thiocyanate (NHSCN) and glycerol were fabricated using a solution casting method. Lithium-based energy storage devices are not environmentally friendly materials, and they are toxic. Thus, proton-conducting materials were used in this work as they are harmless and are smaller than lithium.
View Article and Find Full Text PDFThe influence of dispersing Al-metal complex on the optical properties of PVA was investigated using UV-visible spectroscopy. Polymer composite films with various Al-complex amounts in the PVA matrix were arranged by solution casting technique by means of distilled water as a widespread solvent. The formation of Al-metal complex was verified through Ultraviolet-visible (UV-Vis) and Fourier-transform infrared spectroscopy (FTIR) examinations.
View Article and Find Full Text PDFThis report shows a simple solution cast methodology to prepare plasticized polyvinyl alcohol (PVA)/methylcellulose (MC)-ammonium iodide (NHI) electrolyte at room temperature. The maximum conducting membrane has a conductivity of 3.21 × 10 S/cm.
View Article and Find Full Text PDFIn this work, a pair of biopolymer materials has been used to prepare high ion-conducting electrolytes for energy storage application (ESA). The chitosan:methylcellulose (CS:MC) blend was selected as a host for the ammonium thiocyanate NHSCN dopant salt. Three different concentrations of glycerol was successfully incorporated as a plasticizer into the CS-MC-NHSCN electrolyte system.
View Article and Find Full Text PDFThe fabrication of energy storage EDLC in this work is achieved with the implementation of a conducting chitosan-methylcellulose-NHNO-glycerol polymer electrolyte system. The simple solution cast method has been used to prepare the electrolyte. The impedance of the samples was fitted with equivalent circuits to design the circuit diagram.
View Article and Find Full Text PDFIn this study, biopolymer composite electrolytes based on chitosan:ammonium iodide:Zn(II)-complex plasticized with glycerol were successfully prepared using the solution casting technique. Various electrical and electrochemical parameters of the biopolymer composite electrolytes' films were evaluated prior to device application. The highest conducting plasticized membrane was found to have a conductivity of 1.
View Article and Find Full Text PDFIn this study, porous cationic hydrogen (H) conducting polymer blend electrolytes with an amorphous structure were prepared using a casting technique. Poly(vinyl alcohol) (PVA), chitosan (CS), and NHSCN were used as raw materials. The peak broadening and drop in intensity of the X-ray diffraction (XRD) pattern of the electrolyte systems established the growth of the amorphous phase.
View Article and Find Full Text PDFPlasticized magnesium ion conducting polymer blend electrolytes based on chitosan (CS): polyvinyl alcohol (PVA) was synthesized with a casting technique. The source of ions is magnesium triflate Mg(CFSO), and glycerol was used as a plasticizer. The electrical and electrochemical characteristics were examined.
View Article and Find Full Text PDFIn this study, plasticized films of polyvinyl alcohol (PVA): chitosan (CS) based electrolyte impregnated with ammonium thiocyanate (NHSCN) were successfully prepared using a solution-casting technique. The structural features of the electrolyte films were investigated through the X-ray diffraction (XRD) pattern. The enrichment of the amorphous phase with increasing glycerol concentration was confirmed by observing broad humps.
View Article and Find Full Text PDFIn the present work, chitosan (CS) as a natural biopolymer was used to prepare nanocomposite polymer electrolytes (NCPEs) in order to reduce plastic waste pollution. The plasticized CS-based NCSPE has been prepared via the solution casting technique. The electrical properties of the films were investigated using AC conductivity, dielectric properties, electric modulus, and electrical impedance spectroscopy (EIS).
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