Efficient All-Polymer Solar Cells Enabled by Interface Engineering.

All-polymer solar cells (all-PSCs) are organic solar cells in which both the electron donor and the acceptor are polymers and are considered more promising in large-scale production. Thanks to the polymerizing small molecule acceptor strategy, the power conversion efficiency of all-PSCs has ushered in a leap in recent years. However, due to the electrical properties of polymerized small-molecule acceptors (PSMAs), the FF of the devices is generally not high.