Surface oxidation of commercial activated carbon with enriching carboxyl groups for high-yield electrocatalytic HOproduction.

Two-electron oxygen reduction reaction (2eORR) for HOproduction is regarded as a more ecologically friendly substitute to the anthraquinone method. However, the search of selective and cheap catalysts is still challenging. Herein, we developed a neutral-selective and efficient nonprecious electrocatalyst that was prepared from a commercial activated carbon (AC) by simply microwave-assisted ash impurity elimination and hydrogen peroxide oxidation for surface functional sites optimization.

A visible and colorimetric aptasensor based on DNA-capped single-walled carbon nanotubes for detection of exosomes.

Recently, many studies have shown the potential use of circulating exosomes as novel biomarkers for monitoring and predicting a number of complex diseases, including cancer. However, reliable and cost-effective detection of exosomes in routine clinical settings, still remain a difficult task, mainly due to the lack of adequately easy and fast assay platforms. Therefore, we demonstrate here the development of a visible and simple method for the detection of exosomes by integrating single-walled carbon nanotubes that being excellent water solubility (s-SWCNTs) and aptamer.

MnO Nanofilms on Nitrogen-Doped Hollow Graphene Spheres as a High-Performance Electrocatalyst for Oxygen Reduction Reaction.

Platinum is commonly chosen as an electrocatalyst used for oxygen reduction reaction (ORR). In this study, we report an active catalyst composed of MnO nanofilms grown directly on nitrogen-doped hollow graphene spheres, which exhibits high activity toward ORR with positive onset potential (0.94 V vs RHE), large current density (5.

Sulfur- and nitrogen-doped, ferrocene-derived mesoporous carbons with efficient electrochemical reduction of oxygen.

Development of inexpensive and sustainable cathode catalysts that can efficiently catalyze the oxygen reduction reaction (ORR) is of significance in practical application of fuel cells. Herein we report the synthesis of sulfur and nitrogen dual-doped, ordered mesoporous carbon (SN-OMCs), which shows outstanding ORR electrocatalytic properties. The material was synthesized from a surface-templating process of ferrocene within the channel walls of SBA-15 mesoporous silica by carbonization, followed by in situ heteroatomic doping with sulfur- and nitrogen-containing vapors.

Sulfur and nitrogen co-doped, few-layered graphene oxide as a highly efficient electrocatalyst for the oxygen-reduction reaction.

S and N co-doped, few-layered graphene oxide is synthesized by using pyrimidine and thiophene as precursors for the application of the oxygen reduction reaction (ORR). The dual-doped catalyst with pyrrolic/graphitic N-dominant structures exhibits competitive catalytic activity (10.0 mA cm(-2) kinetic-limiting current density at -0.

Insights into the roles of organic coating in tuning the defect chemistry of monodisperse TiO(2) nanocrystals for tailored properties.

This work initiated a systematic study on the chemical nature of organic coating for monodispersed nanoparticles and its impact on the defect chemistry and the relevant properties. Monodispersed TiO(2) nanoparticles were prepared by a nonhydrolytic sol-gel reaction, which showed features of uniform diameter distribution around 5.2 nm, high crystallinity, and single anatase structure.

Nature of catalytic activities of CoO nanocrystals in thermal decomposition of ammonium perchlorate.

This work addresses the chemical nature of the catalytic activity of X-ray "pure" CoO nanocrystals. All samples were prepared by a solvothermal reaction route. X-ray diffraction indicates the formation of CoO in a cubic rock-salt structure, while infrared spectra and magnetic measurements demonstrate the coexistence of CoO and Co 3O 4.

Synthesis and photoluminescence of well-dispersible anatase TiO2 nanoparticles.

High-purity anatase TiO(2) nanoparticles were prepared using a low-temperature sol-gel route. The as-prepared sample was characterized by X-ray diffraction, transmission electron microscopy, infrared spectroscopy, thermogravimetric analysis, UV-vis spectroscopy, and photoluminescence. It is shown that the as-prepared sample crystallized in a pure anatase phase with an average crystallite size of about 7 nm, and the surfaces were highly hydrated.