Microbial fuel cells (MFCs) have great potential as a new energy technology that utilizes microorganisms to produce electrical energy by decomposing organic matter. A cathode catalyst is key to achieving an accelerated cathodic oxygen reduction reaction (ORR) in MFCs. We prepared a Zr-based metal organic-framework-derived silver-iron co-doped bimetallic material based on electrospun nanofibers by promoting the in situ growth of UiO-66-NH on polyacrylonitrile (PAN) nanofibers and named it as CNFs-Ag/Fe-m:n doped catalyst (m:n were 0, 1:1, 1:2, 1:3, and 2:1, respectively).
View Article and Find Full Text PDFZnic-based metal-organic framework materials (ZIF-8) show great potential and excellent performance in the fields of sensing and catalysis. However, powdered metal-organic framework makes it easy to lose in the process of application. Herein, we use a simple blending electrostatic spinning method to combine ZIF-8 particles with polyacrylonitrile (PAN) nanofibers.
View Article and Find Full Text PDFThe removal of heavy metal ions in wastewater has a great significance to human health and environment protection. Metal organic framework possesses high surface area, rich porosity, tunable pore size and abundant active sites. However, the intrinsic aggregation and fragility of MOF nanoparticles make its poor adsorption and undesirable reusage.
View Article and Find Full Text PDFWearable and shape-adaptive electronic textiles (E-textiles) for human activities detection such as diversity joints motion are highly desired. However, conventional E-textiles still remain great challenges, such as flexibility, air permeability, and large-area fabrication. Here, a fabric E-textile is developed as a self-powered textile for tracking active motion signals.
View Article and Find Full Text PDFLithium metal batteries show great potential in energy storage because of their high energy density. Nevertheless, building a stable solid electrolyte interphase (SEI) and restraining the dendrite growth are difficult to realize with traditional liquid electrolytes. Solid and gel electrolytes are considered promising candidates to restrain the dendrites growth, while they are still limited by low ionic conductivity and incompatible interphases.
View Article and Find Full Text PDFCore-shell-structured BaTiO-poly( tert-butyl acrylate) (P tBA) nanoparticles are successfully prepared by in situ atom transfer radical polymerization of tert-butyl acrylate ( tBA) on BaTiO nanoparticle surface. The thickness of the P tBA shell layer could be controlled by adjusting the feed ratio of tBA to BaTiO. The BaTiO-P tBA nanoparticles are introduced into poly(vinylidene fluoride) (PVDF) matrix to form a BaTiO-P tBA/PVDF nanocomposite.
View Article and Find Full Text PDFMultifunctional electronic textiles (E-textiles) with embedded electric circuits hold great application prospects for future wearable electronics. However, most E-textiles still have critical challenges, including air permeability, satisfactory washability, and mass fabrication. In this work, we fabricate a washable E-textile that addresses all of the concerns and shows its application as a self-powered triboelectric gesture textile for intelligent human-machine interfacing.
View Article and Find Full Text PDFIn recent years, people pay more attention to the protection against chemical warfare agents, due to the increase in the probability of usage of these chemical warfare agents in wars or terrorist attacks. In this work, MgO nanoparticles were in-situ growth on the surface of poly(m-phenylene Isophthalamide) (PMIA) forming a flexible and breathable fabric for the detoxification of mustard gas surrogate. The as-prepared nanofibrous membrane possesses a "flower-like" structure of which endows not only increase the specific surface area of the composite but also prevent the agglomeration of the MgO nanoparticles.
View Article and Find Full Text PDFBroadening the application area of the triboelectric nanogenerators (TENGs) is one of the research emphases in the study of the TENGs, whose output characteristic is high voltage with low current. Here we design a self-powered electrospinning system, which is composed of a rotating-disk TENG (R-TENG), a voltage-doubling rectifying circuit (VDRC), and a simple spinneret. The R-TENG can generate an alternating voltage up to 1400 V.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2013
Tuning and controlling the solid-state luminescence of molecular solids play a key role in developing multi-color displays and tunable dye laser. In this work, we report the tunable blue and red luminescence by the formation of solvate crystals of 1,4-bis(5-phenyl-2-oxazolyl)benzene (POPOP) and 4-(dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM). Upon introduction of guest solvents (chloroform and dichloromethane) into the POPOP and DCM host matrices, the obtained solvate crystals exhibit an alternated stacking arrangement, interaction fashion, and crystal symmetry compared with the pristine chromophore solids.
View Article and Find Full Text PDFIron-oxide nanocrystals (IONCs) have been widely researched, owing to their unique physical and chemical properties. Herein, a new strategy that involves an electrospinning technique with the addition of a surfactant is reported as an effective method for the fabrication of shaped IONCs. With the same precursor compositions, only iron-oxide nanoparticles were obtained by using a sol-gel method without electrospinning.
View Article and Find Full Text PDFA novel magnetic separable composite photocatalytic nanofiber consisting of TiO2 as the major phase, CeO(2-y) and CoFe2O4 as the dopant phase was prepared by sol-gel method and electrospinning technique, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectrum (UV-vis DRS) and vibrating sample magnetometer (VSM). The photocatalytic activity of the resultant CoFe2O4-TiO2 and CeO(2-y)/CoFe2O4-TiO2 nanofibers was evaluated by photodegradation of methylene blue (MB) in an aqueous solution under xenon lamp (the irradiation spectrum energy distribution is similar to sunlight) irradiation in a photochemical reactor. The results showed that the dopant of Ce could affect the absorbance ability and photo-response range.
View Article and Find Full Text PDFA reusable photocatalytic TiO2/CoFe2O4 composite nanofiber was directly formed by using a vertical two-spinneret electrospinning process and sol-gel method, followed by heat treatment at 550 degrees C for 2 h. The high photocatalytic activity of the composite nanofibers depends on the good morphology of the fibers and the appropriate calcination temperature. The crystal structure and magnetic properties of the fibers were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), transmission electron microscope (TEM) and vibrating sample magnetometer (VSM).
View Article and Find Full Text PDFJ Nanosci Nanotechnol
May 2011
Magnetoplumbite-type (M-type) SrRE(x)Fe(12-x)O19 (RE = La and Ce, x = 0-1.0) powders were prepared by a citric acid sol-gel technique and subsequent heat treatment. The crystal structure, grain size and magnetic properties were investigated by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM) and vibrating sample magnetometer (VSM).
View Article and Find Full Text PDFTotal 200 properties related to structural characteristics were employed to represent structures of 400 HA coded proteins of influenza virus as training samples. Some recognition models for HA proteins of avian influenza virus (AIV) were developed using support vector machine (SVM) and linear discriminant analysis (LDA). The results obtained from LDA are as follows: the identification accuracy ( ) for training samples is 99.
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