M-N Configuration on Boron Nitride Boosts Singlet Oxygen Generation via Peroxymonosulfate Activation for Selective Oxidation.

Singlet oxygen (O) is an essential reactive species responsible for selective oxidation of organic matter, especially in Fenton-like processes. However, due to the great limitations in synthesizing catalysts with well-defined active sites, the controllable production and practical application of O remain challenging. Herein, guided by theoretical simulations, a series of boron nitride-based single-atom catalysts (BvBN/M, M=Co, Fe, Cu, Ni and Mn) were synthesized to regulate O generation by activating peroxymonosulfate (PMS).

Separation and reutilization of heavy metal ions in wastewater assisted by p-BN adsorbent.

Extracting heavy metal ions from wastewater has significant implications for both environmental remediation and resource preservation. However, the conventional adsorbents still suffer from incomplete ion removal and low utilization efficiency of the recovered metals. Herein, we present an extraction and reutilization method assisted by porous boron nitride (p-BN) containing high-density N atoms for metal recovery with simultaneous catalyst formation.

Layered double hydroxide/carbonitride heterostructure with potent combination for highly efficient peroxymonosulfate activation.

Iron-based layered double hydroxides (LDHs) have drawn tremendous attention as a promising peroxymonosulfate (PMS) activators, but they still suffer from low efficiencies limited by electrostatic agglomeration and low electronic conductivity. Herein, a MgFeAl layered double hydroxide/carbonitride (LDH/CN) heterostructure was constructed via triggering the interlayer reaction of citric acid (CA) and urea. CA as a structure-directing agent regulated the interlayer anion of MgFeAl-LDH, which enabled an interfacial tuning in the process of coupling with CN.

FeO nanoparticles encapsulated in boron nitride support via N-doped carbon layer as a peroxymonosulfate activator for pollutant degradation: Important role of metal boosted C-N sites.

Developing highly efficient and stable catalysts for peroxymonosulfate (PMS) based advanced oxidation processes (AOPs) are crucial in the field of environmental remediation. In this work, a facile encapsulated-precursor pyrolysis strategy was reported to prepare a competent PMS-activation catalyst, in which uniformly distributed FeO nanoparticles were firmly anchored on porous boron nitride (BN) nanosheets by N-doped carbon shell (NC layer). Taking advantage of strong metal-support interaction, the as-synthesized catalyst (BFA-500) could efficiently activate PMS to achieve 100% removal of 4-chlorophenol (4-CP) in 6 min, and the corresponding turnover frequency (TOF) value was 1-2 orders of magnitude higher than that of the benchmark homogeneous (Fe) and nanoparticle (Fe and FeO) catalysts.