High sensitive detection of Cd, Hg, Pb and Cr in rice based on LA-MPT-OES with optimized excitation regions by two-dimensional characterization of plasma plume.

Direct, rapid and highly sensitive detection of heavy metals in rice is essential to ensure food safety. In this research, a combination of laser ablation and microwave plasma torch optical emission spectrometry (LA-MPT-OES) was proposed. Based on the optimal observation positions, a high sensitivity and direct determination of Cd, Hg, Pb and Cr in rice were realized.

Development of mass spectrometry imaging techniques and its latest applications.

Mass spectrometry imaging (MSI) is a novel molecular imaging technology that collects molecular information from the surface of samples in situ. The spatial distribution and relative content of various compounds can be visualized simultaneously with high spatial resolution. The prominent advantages of MSI promote the active development of ionization technology and its broader applications in diverse fields.

Elucidation of formation mechanism responsible for charge-transfer reagent ions in microwave induced plasma desorption ionization (MIPDI) source.

Charge transfer reagent ions NO and O were major observed in microwave-induced plasma desorption ionization (MIPDI) source. Ions NO was prosperous in the discharge region while ions O generated in the afterglow region. Fundamental aspects of conditions that controlled MIPDI were addressed here to help understand the specific role of atmospheric components for charge transfer reagent ions formation.

Advances in pretreatment and analysis methods of aromatic hydrocarbons in soil.

Benzene compounds that are prevalent in the soil as organic pollutants mainly include BTEX (benzene, toluene, ethylbenzene, and three xylene isomers) and PAHs (polycyclic aromatic hydrocarbons). These pose a severe threat to many aspects of human health. Therefore, the accurate measurement of BTEX and PAHs concentrations in the soil is of great importance.

Effective N capture by aryl cations at ambient temperature and pressure.

Here, we show that molecular N2 was efficiently captured by organic arylium cations in a well-defined manner at ambient pressure and temperature, which was monitored by on-line mass spectrometry analysis. A kinetic picture was proposed to disclose the principle of the ion-molecule reaction behavior for exclusive aryldiazonium production. The observation has an implication for direct nitrogen fixation into an organic framework via the intermediacy of such cationic species.

Synergetic effect of laser and micro-fabricated glow discharge plasma in a new ion source for ambient mass spectrometry.

A new ambient ionization technique named laser ablation micro-fabricated glow discharge plasma (LA-MFGDP) was developed for mass spectrometry in this study. This technique used low energy laser for sample ablation and ionized sample aerosol with MFGDP in sequence. The combination of laser ablation and MFGDP exhibited a synergetic effect that significantly improved the performance of MFGDP.

Methylation in combination with temperature programming enables rapid identification of polysaccharides by ambient micro-fabrication glow discharge plasma (MFGDP) desorption ionization mass spectrometry.

Obtaining the fingerprints of polysaccharides was known to be notoriously difficult by ambient mass spectrometry due to their resistance for desorption and ionization. Ambient mass spectrometry technology has recently been recognized as a quick analysis tool for obtaining fingerprints, which is attributed to its characteristics of no sample pretreatment and easy operation under atmospheric pressure. However, it still remains a challenge for accurate identification of the fingerprints of macromolecular polysaccharides by ambient micro-fabrication glow discharge plasma (MFGDP).

Efficient degradation of Fipronil in water by microwave-induced argon plasma: Mechanism and degradation pathways.

Fipronil and its metabolites are potentially harmful to the ecological environment and have chronic neurotoxic effects, which makes it to be classified as class C carcinogens. Fipronil has been banned from agricultural use in China since 2009, but its residue remains in the environment. Therefore, an efficient and economical method is urgently needed to degrade fipronil residues in the environment.

Interpretation of Ionization Mechanism Responsible for Reagent Ion and Analyte Formation in Microwave-Induced Plasma Desorption Ionization Mass Spectrometry.

Ambient desorption/ionization (ADI) sources coupled to mass spectrometer have gained increasing interest in the field of analytical chemistry for its fast and direct analysis of samples. Among many ADI sources, plasma-based ADI sources are an important branch. Despite its extensive use in mass spectrometry analysis, the ionization mechanism of these sources still remain uncertain.

Development of microwave plasma proton transfer reaction mass spectrometry (MWP-PTR-MS) for on-line monitoring of volatile organic compounds: Design, characterization and performance evaluation.

Proton transfer reaction mass spectrometry (PTR-MS) is a revolutionary on-line VOCs monitoring method. In this study, a new microwave plasma-based proton transfer reaction mass spectrometry (MWP-PTR-MS) is developed. The MWP consists of a surfatron type resonator and a cooperative ion extraction device to achieve high efficiency production of hydronium ions.

A mechanism study of positive ionization processes in flowing atmospheric-pressure afterglow (FAPA) ambient ion source with controlled plasma and ambient conditions.

Although plasma based ambient desorption/ionization (ADI) sources have been widely used for direct analysis of complex samples, mass spectrometric imaging, high throughput screening etc., the ionization mechanism of plasma-based ADI remains a mystery by now. In this report, a targeted study was conducted aiming at a better understanding of the ionization processes of plasma-based ambient desorption ionization source.

Rapidly monitoring the quality of flavoring essence based on microwave-induced plasma ionization mass spectrometry and multivariate statistical analysis.

Microwave-induced plasma ionization mass spectrometry (MIPI-MS) combined with multivariate statistical analysis was first applied to rapidly monitor the quality of tobacco flavoring essence. A small isolation and reaction chamber was set up between the ion source and the injection port of mass spectrometer to effectively eliminate the interference of external environment in the process of analyzing samples. The improved experimental apparatus (MIPI-MS) could achieve online and high-throughput analysis, with minimal sample preparation steps.

A Novel Microwave-Induced Plasma Ionization Source for Ion Mobility Spectrometry.

This work demonstrates the application of a novel microwave induced plasma ionization (MIPI) source to ion mobility spectrometry (IMS). The MIPI source, called Surfatron, is composed of a copper cavity and a hollow quartz discharge tube. The ion mobility spectrum of synthetics air has a main peak with reduced mobility of 2.

Fiber Optic Surface Plasmon Resonance-Based Biosensor Technique: Fabrication, Advancement, and Application.

Fiber optic-based biosensors with surface plasmon resonance (SPR) technology are advanced label-free optical biosensing methods. They have brought tremendous progress in the sensing of various chemical and biological species. This review summarizes four sensing configurations (prism, grating, waveguide, and fiber optic) with two ways, attenuated total reflection (ATR) and diffraction, to excite the surface plasmons.