The micro-sintering method was used to determine the sintering basic characteristics of iron ore with Zn contents from 0 to 4%, the influence mechanism of Zn on sintering basic characteristics of iron ore was clarified by means of thermodynamic analysis and first-principles calculations. The results showed that (1) increasing the ZnO and ZnFeO content increased the lowest assimilation temperature (LAT) but decreased the index of liquid phase fluidity (ILF) of iron ore. The addition of ZnS had no obvious effect on LAT but increased the LIF of iron ore.
View Article and Find Full Text PDFIn order to increase the utilization rate of stainless steel slag, reduce storage needs, and mitigate environmental impacts, this study replaces a portion of limestone with varying amounts of stainless steel slag in the calcination of Portland cement clinker. The study primarily examines the influence of stainless steel slag on the phase composition, microstructure, compressive strength, and free calcium oxide (ƒ-CaO) content of Portland cement clinker. The results show the following: (1) Using stainless steel slag to calcine Portland cement clinker can lower the calcination temperature, reducing industrial production costs and energy consumption.
View Article and Find Full Text PDFMaterials (Basel)
March 2023
To elucidate the behavior of fluoride evaporation in an electroslag remelting process, the non-isothermal evaporation of the low-fluoride CaF-CaO-AlO-MgO-TiO-(NaO-KO) slag is studied using thermogravimetric analysis. The evaporation law of the melted slag is further verified using thermodynamic calculations. Fourier transformation infrared (FTIR) spectroscopy is used to evaluate the change in slag structure.
View Article and Find Full Text PDFThe coal tends to be affected by the water vapor from quenching coke process in the pyrolysis process during the coal carbonization process and in turn causes the variation of physicochemical properties of semicoke. The preparation of semicoke based on different pyrolysis temperatures and water vapor content was carried out in order to investigate the influence of water vaper on physicochemical properties of the pyrolytic semicoke, combined with specific surface area analysis and thermal analysis to study the pore structure and combustion properties of semicoke. The morphology of the semicoke and the alteration rule of carbon-containing functional groups were analyzed by scanning electron microscopy and X-ray photoelectron spectroscopy.
View Article and Find Full Text PDFThe isothermal kinetics of fluoride evaporation from CaF-CaO-AlO-MgO-TiO-(LiO) slag with varying LiO content were investigated in the temperature range 1743-1803 K by thermogravimetric analysis. Thermodynamic calculations and viscosity measurements were applied for studying the evaporation mechanism of fluoride. The results showed that the evaporation ratio increases with increasing LiO content and temperature.
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