Low capacity and poor cycle stability greatly inhibit the development of zinc-iodine batteries. Herein, a high-performance Zn-iodine battery has been reached by designing and optimizing both electrode and electrolyte. The Br is introduced as the activator to trigger I, and coupled with I forming interhalogen to stabilize I to achieve a four-electron reaction, which greatly promotes the capacity.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2023
Zn metal anode suffers from dendrite growth and side reactions during cycling, significantly deteriorating the lifespan of aqueous Zn metal batteries. Herein, we introduced an ultrathin and ultra-flat Sb O molecular crystal layer to stabilize Zn anode. The in situ optical and atomic force microscopes observations show that such a 10 nm Sb O thin layer could ensure uniform under-layer Zn deposition with suppressed tip growth effect, while the traditional WO layer undergoes an uncontrolled up-layer Zn deposition.
View Article and Find Full Text PDFTwo-dimensional (2D) materials, which possess robust nanochannels, high flux and allow scalable fabrication, provide new platforms for nanofluids. Highly efficient ionic conductivity can facilitate the application of nanofluidic devices for modern energy conversion and ionic sieving. Herein, we propose a novel strategy of building an intercalation crystal structure with negative surface charge and mobile interlamellar ions via aliovalent substitution to boost ionic conductivity.
View Article and Find Full Text PDFChina's low fertility rates are a major concern across all sectors of society. Fertility is a major issue related to economy, society and family development. Based on social norms theory, this paper explores the influence of social norms on individuals' fertility intentions from two perspectives: spatial proximity and social proximity.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2022
As a new class of solid electrolytes, halide solid electrolytes have the advantages of high ionic conductivity at room temperature, stability to high-voltage cathodes, and good deformability, but they generally show a problem of being unstable to a lithium anode. Here, we report the use of LiN as an interface modification layer to improve the interfacial stability of LiZrCl to the Li anode. We found that commercial LiN can be easily transformed into an α-phase and a β-phase by ball-milling and annealing, respectively, in which β-phase LiN simultaneously has high room-temperature ionic conductivity and good stability to both Li and LiZrCl, making it a good choice for an artificial interface layer material.
View Article and Find Full Text PDFInt J Environ Res Public Health
April 2022
This study analyses the effect of air pollution on the settlement intention of migrants in China. In recent years, the willingness of residents to migrate induced by air pollution has received a lot of attention from academics. By matching information from the China Migrants Dynamic Survey from 2015 to 2017 with the air quality index (AQI), we used the Probit model to assess the impact of air pollution on the settlement intentions of migrants with different socioeconomic statuses.
View Article and Find Full Text PDFLi-ion batteries, the most-popular secondary battery, are typically electrochemical systems controlled by ion-insertion dynamics. The battery dynamics involve mass transport, charge transfer, ion-electron coupled reactions, electrolyte penetration, ion solvation, and interfacial evolution. However, it is difficult for the traditional electrochemical methods to capture the accurate and individual details of the dynamic processes in "black box" batteries; instead, only the net result of multi-factors on the whole scale.
View Article and Find Full Text PDFIron corrosion causes a great damage to the economy due to the function attenuation of iron-based devices. However, the corrosion products can be used as active materials for some electrocatalytic reactions, such as oxygen evolution reaction (OER). Herein, the oxygen corrosion on Fe foams (FF) to synthesize effective self-supporting electrocatalysts for OER, leading to "turning waste into treasure," is regulated.
View Article and Find Full Text PDFBackground: Glioblastoma (GBM) is a subclass of brain malignancy with unsatisfactory prognosis. MicroRNAs (miRNAs) are a group of non-coding RNAs (ncRNAs) that exert key function on tumorigenesis and tumor development.
Purposes: The purpose of this work was to unravel the biological behavior and mechanism of miR-1204 in GBM.
Developing facile methods to construct hierarchical-structured transition metal phosphides is beneficial for achieving high-efficiency hydrogen evolution catalysts. Herein, a self-template strategy of hydrothermal treatment of solid Ni-Co glycerate nanospheres followed by phosphorization is delivered to synthesize hierarchical NiCoP hollow nanoflowers with ultrathin nanosheet assembly. The microstructure of NiCoP can be availably tailored by adjusting the hydrothermal treatment temperature through affecting the hydrolysis process of Ni-Co glycerate nanospheres and the occurred Kirkendall effect.
View Article and Find Full Text PDFDesigning efficient nonprecious catalysts with pH-universal hydrogen evolution reaction (HER) performance is of importance for boosting water splitting. Herein, a self-template strategy based on Ni-Co-glycerates is developed to prepare bimetallic Ni-Co-P microflowers with ultrathin nanosheet arrays. The highly porous core-shell structure gives rise to affluent mass transfer channels and availably prevents the aggregation of nanosheets, while the ultrathin nanosheets are favorable for producing abundant active sites.
View Article and Find Full Text PDFAm J Respir Cell Mol Biol
August 2017
Runt-related transcription factor 1 (RUNX1), a transcription factor expressed in multiple organs, plays important roles in embryonic development and hematopoiesis. Although RUNX1 is highly expressed in pulmonary tissues, its roles in lung function and homeostasis are unknown. We sought to assess the role of RUNX1 in lung development and inflammation after LPS challenge.
View Article and Find Full Text PDFXi Bao Yu Fen Zi Mian Yi Xue Za Zhi
February 2017
Objective To study the expression levels of TNF-α and IL-1β in the lung tissues of acute respiratory distress syndrome (ARDS) mice and their relationships with the severity of lung injury in the mice. Methods A mouse model of ARDS was induced by lipopolysaccharide (LPS). The morphological changes of lung tissue was observed by HE staining, and the lung injury score was calculated.
View Article and Find Full Text PDFBackground: The incidence of breast cancer in RA patients remains controversial. Thus we performed a meta-analysis to investigate the impact of RA on breast cancer.
Methods: Published literature was available from PubMed, Embase, and Cochrane Library.