Self-healing of electrical damage in insulating robust epoxy containing dynamic fluorine-substituted carbamate bonds for green dielectrics.

Power systems and electrical grids are critical for the development of renewable energy. Electrical treeing is one of the major factors that lead to electrical damage in insulating dielectrics and decline in the reliability of power equipment and ultimately results in catastrophic failure. Here, we demonstrate that bulk epoxy damaged by electrical treeing is able to efficiently heal repeatedly to recover its original robust performance.

Supramolecular metallomesogens. Self-organization of an H-bonded tetrameric assembly into columnar phase from single component.

The first example of supramolecular metallomesogens derived from palladium complexes exhibiting columnar phase is reported, and the formation of the mesophase is induced by H-bonding in a tetrameric assembly.