Publications by authors named "Jianguo Si"

Superconductivity has been one of the focal points in medium and high-entropy alloys (MEAs-HEAs) since the discovery of the body-centered cubic (bcc) HEA superconductor in 2014. Until now, the superconducting transition temperature (T_{c}) of most MEA and HEA superconductors has not exceeded 10 K. Here, we report a TaNbHfZr bulk MEA superconductor crystallized in the BCC structure with a T_{c} of 15.

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Article Synopsis
  • High energy density and long cycle lifespan of aqueous zinc ion batteries are limited by issues with cathode materials and zinc dendrite growth.
  • A defect-rich VS cathode material was created through electrochemical defect engineering, improving zinc transport and achieving impressive rate capabilities.
  • Introducing an external magnetic field significantly reduces zinc dendrite growth, enhancing cycling stability and allowing the Zn-VS full cell to achieve long-lasting performance and high energy density after extensive cycling.
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Materials with superconductivity and a nontrivial band structure near the Fermi level are promising candidates in realizing topological superconductivity. Using first-principles calculations, we systematically investigated the stability, mechanical properties, superconductivity, electronic structures, and topological states of hexagonal TaC and NbC. The results show that they are stable and have excellent mechanical properties.

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  • The study explores the Kondo lattice phenomenon, which involves a dense array of local moments interacting with conduction electrons, and emphasizes that knowledge in this area is still developing.
  • The researchers demonstrate that adding lead (Pb) to the material 1T-TaS causes a transition from an insulating state to a sharp Kondo resonance, indicating a change in electronic behavior.
  • By increasing the concentration of Pb, the characteristics of the localized electrons change, affecting their interaction with the Kondo resonance, which offers insights for future studies on electronic states in layered materials.
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3D anisotropic functional properties (such as magnetic, electrical, thermal, and optical properties, etc.) in a single material are not only beneficial to the multipurpose of a material, but also helpful to enrich the regulatory dimensionality of functional materials. Herein, a colossal 3D electrical anisotropy of layered MAB-phase MoAlB single crystal is introduced and dissected.

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Hexagon-like MAX-phase VAlC single crystals grown by a high-temperature flux method were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDX). We report, for the first time, the first-order Raman spectra (RS) of VAlC single crystals experimentally and theoretically. Via the combination of the results of thermogravimetric analysis, differential scanning calorimetry, XRD, FE-SEM, and EDX, the oxidation performance and mechanism of VAlC single crystals between 300 and 1473 K in air were clarified.

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1T phase MoS possesses higher conductivity than the 2H phase, which is a key parameter of electrochemical performance for lithium ion batteries (LIBs). Herein, a 1T-MoS /C hybrid is successfully synthesized through facile hydrothermal method with a proper glucose additive. The synthesized hybrid material is composed of smaller and fewer-layer 1T-MoS nanosheets covered by thin carbon layers with an enlarged interlayer spacing of 0.

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