Superconductivity has been one of the focal points in medium and high-entropy alloys (MEAs-HEAs) since the discovery of the body-centered cubic (bcc) HEA superconductor in 2014. Until now, the superconducting transition temperature (T_{c}) of most MEA and HEA superconductors has not exceeded 10 K. Here, we report a TaNbHfZr bulk MEA superconductor crystallized in the BCC structure with a T_{c} of 15.
View Article and Find Full Text PDFMaterials with superconductivity and a nontrivial band structure near the Fermi level are promising candidates in realizing topological superconductivity. Using first-principles calculations, we systematically investigated the stability, mechanical properties, superconductivity, electronic structures, and topological states of hexagonal TaC and NbC. The results show that they are stable and have excellent mechanical properties.
View Article and Find Full Text PDF3D anisotropic functional properties (such as magnetic, electrical, thermal, and optical properties, etc.) in a single material are not only beneficial to the multipurpose of a material, but also helpful to enrich the regulatory dimensionality of functional materials. Herein, a colossal 3D electrical anisotropy of layered MAB-phase MoAlB single crystal is introduced and dissected.
View Article and Find Full Text PDFHexagon-like MAX-phase VAlC single crystals grown by a high-temperature flux method were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDX). We report, for the first time, the first-order Raman spectra (RS) of VAlC single crystals experimentally and theoretically. Via the combination of the results of thermogravimetric analysis, differential scanning calorimetry, XRD, FE-SEM, and EDX, the oxidation performance and mechanism of VAlC single crystals between 300 and 1473 K in air were clarified.
View Article and Find Full Text PDF1T phase MoS possesses higher conductivity than the 2H phase, which is a key parameter of electrochemical performance for lithium ion batteries (LIBs). Herein, a 1T-MoS /C hybrid is successfully synthesized through facile hydrothermal method with a proper glucose additive. The synthesized hybrid material is composed of smaller and fewer-layer 1T-MoS nanosheets covered by thin carbon layers with an enlarged interlayer spacing of 0.
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