Effects of dimethylarsenate coprecipitation with ferrihydrite on Fe(II)-induced mineral transformation and the release of dimethylarsenate.

Organoarsenicals are toxic pollutants of global concern, and their environmental geochemical behavior might be greatly controlled by iron (Fe) (hydr)oxides through coprecipitation, which is rarely investigated. Here, the effects of the incorporation of dimethylarsenate (DMAs(V)), a typical organoarsenical, into the ferrihydrite (Fh) structure on the mineral physicochemical properties and Fe(II)-induced phase transformation of DMAs(V)-Fh coprecipitates with As/Fe molar ratios up to 0.0876 ± 0.

Clinical Efficacy of Tuina Therapy for Acute Lumbar Sprain: A Bayesian Network Meta-Analysis Based on Randomized Controlled Trials.

Purpose: Traditional Chinese medicine possesses distinct advantages in the treatment of acute lumbar sprains, and Tuina (Chinese massage) is a commonly employed therapeutic method. This study employed a Bayesian meta-analysis to assess the efficacy and safety of Tuina therapy for acute lumbar sprain with the aim of providing more evidence-based medical substantiation for clinical practice.

Patients And Methods: Randomized controlled trials of Tuina therapy for acute lumbar sprains published in CNKI, CSPD, CCD, CBM, PubMed, Embase, Cochrane Library, and Web of Science were searched up to August 7, 2024.

Anti-seepage reinforcement property and pollution control effect of bio-cemented fracture zone in electrolytic manganese residue dump.

The heavy metal (HM) pollutants in electrolytic manganese residue (EMR) can easily diffuse through the seepage channel of the dump under the leaching action of rainfall. Particularly, the fracture zone, as one of the widely distributed seepage channels in the manganese residue dump (MRD), poses a greater threat to the ecological environment due to its weak mechanical properties, strong ductility, and numerous fractures. In this study, the microbially induced calcium carbonate precipitation (MICP) method was used for anti-seepage reinforcement of the fracture zone in an MRD to be constructed.

Chromium(VI) Adsorption and Reduction in Soils under Anoxic Conditions: The Relative Roles of Iron (oxyhr)oxides, Iron(II), Organic Matters, and Microbes.

Chromium (Cr) transformation in soils mediated by iron (Fe) (oxyhr)oxides, Fe(II), organic matter (OM), and microbes is largely unexplored. Here, their coupling processes and mechanisms were investigated during anoxic incubation experiments of four Cr(VI) spiked soil samples with distinct physicochemical properties from the tropical and subtropical regions of China. It demonstrates that easily oxidizable organic carbon (EOC, 55-84%) and microbes (16-48%) drive Cr(VI) reduction in soils enriched with goethite and/or hematite, among which in dryland soils microbial sulfate reduction may also be involved.

Highly efficient removal of aqueous phosphate via iron-manganese fabricated biochar: Performance and mechanism.

Biochar (BC) has emerged as a potential solution to phosphate removal from wastewater primarily resulting from global overuse of fertilizers. Further modification by embedment of iron (Fe)-manganese (Mn) oxides on BC can enhance phosphate removal; however, the modification method serves as a vital factor underlying distinctive removal performances and mechanisms, which have yet been systematically examined. Herein, two Fe-Mn modified BC, Fe/MnBC (comprised of FeO and MnO) and Fe-MnBC (comprised of MnFeO), were comprehensively investigated for gaining insights into the unsolved perspectives.

Oxalate modification enabled advanced phosphate removal of nZVI: In Situ formed surface ternary complex and altered multi-stage adsorption process.

Nano zero-valent iron (nZVI) is a promising phosphate adsorbent for advanced phosphate removal. However, the rapid passivation of nZVI and the low activity of adsorption sites seriously limit its phosphate removal performance, accounting for its inapplicability to meet the emission criteria of 0.1 mg P/L phosphate.

Unraveling the impact of Spartina alterniflora invasion on greenhouse gas production and emissions in coastal saltmarshes: New insights from dissolved organic matter characteristics and surface-porewater interactions.

Saltmarshes along the Chinese coast are threatened by the invasion of Spartina alterniflora (S. alterniflora). This study was carried out in the Andong Shoal, Hangzhou Bay, China, with the aim of comprehending the intricate impacts of S.

Cadmium Isotope Fractionation during Adsorption onto Edge Sites and Vacancies in Phyllomanganate.

Cadmium (Cd) geochemical behavior is strongly influenced by its adsorption onto natural phyllomanganates, which contain both layer edge sites and vacancies; however, Cd isotope fractionation mechanisms at these sites have not yet been addressed. In the present work, Cd isotope fractionation during adsorption onto hexagonal (containing both types of sites) and triclinic birnessite (almost only edge sites) was investigated using a combination of batch adsorption experiments, extended X-ray absorption fine structure (EXAFS) spectroscopy, surface complexation modeling, and density functional theory (DFT) calculations. Light Cd isotopes are preferentially enriched on solid surfaces, and the isotope fractionation induced by Cd adsorption on edge sites (ΔCd = -1.

MgO-based supersulfated cement with different industrial by-product gypsum: Experiments and molecular dynamics simulation.

Super sulfate cement (SSC) emerges as a sustainable alternative to ordinary Portland cement, boasting minimal carbon emissions and exceptional performance. As the quest for eco-friendly alternatives intensifies, there's a growing focus on exploring alkaline and sulfate activators conducive to SSC's environmental goals. This study delves into the viability of utilizing MgO as an alkaline activator in producing MgO-based supersulfated cement, while also investigating the impact of various industrial by-product gypsums on its performance.

Environmental performance of unfired bricks produced from co-disposal of mine tailings and municipal solid waste incineration fly ash based on comprehensive leaching tests.

The potential leaching of heavy metals is a crucial concern for construction materials produced from solidification/stabilization (S/S) treatment of wastes. This study comprehensively evaluated the leaching characteristics of heavy metals from the unfired bricks produced from co-disposal of Pb-Zn mine tailings and municipal solid waste incineration fly ash using batch, sequential, and semi-dynamic leaching tests. The results show that S/S treatment drastically reduced the leachability of heavy metals from the unfired bricks through lowering their distribution in the acid-soluble fraction.

A bibliometric analysis of autism spectrum disorder signaling pathways research in the past decade.

Background: This study employs bibliometric methods to comprehensively understand the fundamental structure of research about Autism Spectrum Disorder (ASD) Signaling Pathways by examining key indicators such as nations, institutions, journals, authors, and keywords.

Methodology: We utilized the WoScc database to retrieve literature relevant to ASD Signaling Pathways published between 2013 and 2023. Through visual analysis and tools like CiteSpace and VosViewer, we explored nations, institutions, journals, authors, and keywords, thereby constructing relevant networks.

Mechanism and effectiveness of enzymatically induced phosphate precipitation (EIPP) in stabilizing coexisting lead, zinc, and cadmium in tailings.

Lead-zinc (Pb-Zn) tailings ponds carry the risk of multiple heavy metals (HMs) contamination and pile destabilization. This poses requirements for in-situ applicable, low-distribution, and effective stabilization/solidification (S/S) methods. For this, the novel enzymatically induced phosphate precipitation (EIPP) method was implemented in this study.

Effectiveness of musculoskeletal manipulations in patients with neck pain: a protocol for a systematic review and network meta-analysis.

Introduction: Neck pain is a common problem that severely affects physical and mental health. While musculoskeletal manipulations are recommended as the first-line treatment for adults with neck pain, the comparative effectiveness of different musculoskeletal manipulations remains unclear. This systematic review and network meta-analysis of randomised controlled trials (RCTs) will compare the effectiveness of different types of musculoskeletal manipulations, with the overarching aim of guiding clinical practice.

Effects of online exercise intervention on physical and mental conditions in young adults with chronic neck pain.

This study aimed to compare the efficacy of online exercise therapy with conventional exercise therapy for young adults with chronic neck pain. A randomized clinical trial recruiting 35 university students with self-reported chronic neck pain was conducted. The experimental group receiving 6-week online exercise therapy and active control group receiving the same face-to-face conventional exercise therapy.

Characteristics of iron (hydr)oxides and Cr(VI) retention mechanisms in soils from tropical and subtropical areas of China.

Though both iron (hydr)oxides and soil organic matter (SOM) significantly influence heavy metal behaviors in soils, studies on the characteristics of natural minerals and the synergic effects of the two on Cr(VI) transformation are limited. This study investigated Cr(VI) retention mechanisms in four soils from tropical and subtropical regions of China based on a comprehensive characterization of Fe (hydr)oxides. These soils exhibited varying quantities of hematite, ferrihydrite and goethite, with distinct Al substitution levels and varied exposed crystallographic facets.

Effect of COVID-19 on autism spectrum disorders: A bibliometric analysis based on original articles.

Background: The objective of this bibliometric inquiry was to scrutinize domains that delve into the repercussions of the 2019 coronavirus disease (COVID-19) pandemic on individuals afflicted with autism spectrum disorder (ASD), worldwide scholarly findings of interrelated research, and forthcoming trajectories.

Methods: To conduct a literature analysis, use the web of science core collection database, search for ASD and COVID-19-related literature published Utilize CiteSpace and VosViewer to visually analyze documents and create networks of authors, organizations. The CiteSpace and VosViewer to visually analyze documents and create networks of authors, organizations, countries, and keywords.

Exploring the migration and transformation behaviors of heavy metals and ammonia nitrogen from electrolytic manganese residue to agricultural soils through column leaching test.

Heavy metals (HMs) and ammonia nitrogen (AN) leaching from electrolytic manganese residue (EMR) result in the contamination of agricultural soils and water bodies. Batch and column leaching tests were conducted to simulate the release of HMs and AN in EMR during precipitation, as well as their migration and transformation in agricultural soils. The results show that Mn, AN, Cd, Ni, and Zn present in the EMR had high acid soluble fraction (un-fixed AN) content, and the leachability of Mn and AN was significantly higher than that of other hazardous elements.

Bibliometric Analysis of Research Trends on Tuina Manipulation for Neck Pain Treatment Over the Past 10 Years.

Tuina is an effective treatment for neck pain (NP). However, there has been no bibliometric analysis of the global application and emerging trends of tuina performed for NP. Therefore, this study aimed to provide an overview of the current state and future trends in the field.

Unraveling the cation adsorption of geopolymer binder: A molecular dynamics study.

Geopolymers play a significant role in remediation of heavy metal contamination and are attracting increasing interests. Sodium aluminosilicate hydrate (NASH) is the prime hydration substance of geopolymers which exhibits excellent adsorption capacity, however, the mechanism of metal cation adsorption at the NASH interface remains unclear. In this study, the adsorption behavior of cations at the NASH interface was investigated in depth, and the effects of Si/Al ratios, ion concentration and ion type on adsorption behavior were also analyzed.

Physicochemical and pozzolanic properties of municipal solid waste incineration fly ash with different pretreatments.

Swelling caused by gas generated from municipal solid waste incineration fly ash (MSWIFA) when it is mixed with alkali limits its uses. Besides, the leaching of anion salts and heavy metals contained in MSWIFA poses a high risk to environment. This study presents the feasibility of a one-step alkaline washing, one-step thermal quenching and two-step combination of alkaline washing and thermal quenching pretreatment methods in altering the key properties of MSWIFA for promoting its reusability.

Stabilization and strengthening of chromium(VI)-contaminated soil via magnesium ascorbyl phosphate (MAP) and phytase addition.

Cr(VI) contamination of soil threatens the environment and reduces soil strength. Therefore, both Cr(VI) stabilization and soil reinforcement should be considered in site remediation for future construction. This study investigated a biochemical treatment process using magnesium ascorbyl phosphate (MAP) and phytase.

Solidification and stabilization of Pb-Zn mine tailing with municipal solid waste incineration fly ash and ground granulated blast-furnace slag for unfired brick fabrication.

The mismanaged and abandoned mine tailings are an important source of heavy metal pollution in the mining regions, and there is a significant need to develop technically, environmentally, and economically feasible and sustainable solutions to manage them. This study explored the solidification and stabilization of the tailing from an abandoned Pb-Zn mine using municipal solid waste incineration fly ash (MSWIFA) blended with ground granulated blast-furnace slag (GGBFS) for fabricating unfired bricks, and systematically characterized the products' mechanical and environmental performance. Various hydration products, such as ettringite, portlandite, and hydrotalcite, were formed in the unfired bricks in the solidification and stabilization process, which enhance the physical strength of unfired bricks and help immobilize the heavy metals.