Core-shell Pd-P@Pt-Ni nanoparticles with enhanced activity and durability as anode electrocatalyst for methanol oxidation reaction.

Pd-P@Pt-Ni core-shell nanoparticles, which consisted of a Pd-P alloy as a core and Pt-Ni thin layer as a shell, were explored as electrocatalysts for methanol oxidation reaction. The crystallographic information and the electronic properties were fully investigated by X-ray diffraction and X-ray photoelectron spectroscopy. In the methanol electrooxidation reaction, the particles showed high catalytic activity and strong resistance to the poisoning carbonaceous species in comparison with those of commercial Pt/C and the as-prepared Pt/C catalysts.

Giant Room-Temperature Magnetodielectric Response in a MOF at 0.1 Tesla.

A giant room-temperature magnetodielectric (MD) response upon the application of a small magnetic field is of fundamental importance for the practical application of a new generation of devices. Here, the giant room-temperature magnetodielectric response is demonstrated in the metal-organic framework (MOF) of [NH (CH ) ] [Fe Fe Ni (HCOO) ] (x ≈ 0.63-0.

Probing the structural flexibility of MOFs by constructing metal oxide@MOF-based heterostructures for size-selective photoelectrochemical response.

It is becoming a challenge to achieve simpler characterization and wider application of flexible metal organic frameworks (MOFs) exhibiting the gate-opening or breathing behavior. Herein, we designed an intelligent MOF-based system where the gate-opening or breathing behavior of MOFs can be facially visualized in solution. Two types of metal oxide@MOF core-shell heterostructures, ZnO@ZIF-7 and ZnO@ZIF-71, were prepared using ZnO nanorods as self-sacrificial templates.