Superhydrophobic nanocellulose-based self-assembled flexible SERS substrates for pesticide detection.

Flexible surface-enhanced Raman scattering (SERS) substrates that provide simple sampling are helpful for the on-site detection of explosive contamination, pesticide residues on food surfaces, and water pollution in public spaces. Using superhydrophobic nanocellulose-based film as the support, 2D flexible SERS substrates that integrated sampling, enrichment, and detection were successfully fabricated via the solvent-induced evaporation method. This approach enabled the co-loading of two plasmonic nanoparticles with different sizes and shapes.

Bifunctional Nanocellulose@MOF composite aerogel for selective fluorescent detection and efficient removal of tetracycline.

The antibiotic tetracycline (TC) significantly pollutes water bodies, adversely impacting ecosystems and human health. In this work, a bifunctional platform for simultaneous detection and removal of TC was successfully constructed by in-situ growth of Zr-MOF in BC microspheres. The in-situ growth ensured the stability, while the design of the aerogel microspheres improved the processability, convenience, and recyclability.

Self-supporting and hierarchical porous membrane of bacterial nanocellulose@metal-organic framework for ultra-high adsorption of Congo red.

The widespread use of synthetic dyes has serious implications for both the environment and human health. Therefore, there is an urgent need for the development of novel, high-efficiency adsorbents for these dyes. In this study, a Zirconium-based metal-organic framework (MOF) with controllable morphology was in-situ grown on bacterial nanocellulose (BC) via a solvothermal method.

Superelastic carbon aerogels with anisotropic and hierarchically-enhanced cellular structure for wearable piezoresistive sensors.

Elastic carbon aerogels have promising applications in the field of wearable sensors. Herein, a new strategy for preparing carbon aerogels with excellent compressive strength and strain, shape recovery, and fatigue resistance was proposed based on the structure design and carbonization optimization of nanocellulose-based precursor aerogels. By the combination of directional freezing and zinc ion cross-linking, bacterial cellulose (BC)/alginate (SA) composite aerogels with high elasticity and compressive strength were first achieved.

Nanocellulose-based membranes with pH- and temperature-responsive pore size for selective separation.

Smart gating membranes have drawn much attention due to the controllable pore structure. Herein, a smart gating membrane with dual responsiveness was prepared from bacteria cellulose (BC) grafted with pH- and temperature-responsive polymers. By external stimulation, the average pore size of the membrane can be controlled from 33.

In situ growth of AgS quantum dots on cellulose nanocrystals and their near-infrared bioimaging performance.

Elongated nanoparticles show distinct advantages over spherical nanoparticles in bioimaging because of surface area-to-volume, rate of clearance from the body and elimination mechanism. In this work, we investigated the fluorescence emission properties of the hybrid system by decorating silver sulfide quantum dots (AgS QDs) in situ on the surface of cellulose nanocrystal (CNC) with unique rod shape, modifiability and biocompatibility. This water-dispersible fluorescent probe has both absorption and fluorescence in near-infrared (NIR) region.

Superelastic chitin nanofibril/chitosan aerogel for effective circulating and continuous oil-water separation.

Elastic and hydrophobic aerogels have received a lot of attention in dealing with the increasing oil pollution due to their recyclable properties. Herein, we present an ultralight and superelastic aerogel with highly oriented polygon structure based on chitin nanofibril (ChNF) and chitosan (CS) by directional freezing. The chemical cross-linking enables good mechanical strength at low aerogel density.

A smart gating nanocellulose membrane showing selective separation and self-cleaning performance.

A smart gating membrane based on thermal-sensitive poly (N-isopropyl acrylamide) (PNIPAM)-grafted nanocellulose and carbon nanotube (CNT) was prepared. The presence of PNIPAM shell on cellulose nanofibrils (CNFs) endow the composite membrane with thermal responsiveness. By external stimulation, an increase temperature from 10 °C to 70 °C allows the average pore size of the membrane to be controlled from 28 nm to 110 nm, as well as the water permeance from 440 L·m·h·bar to 1088 L·m·h·bar.

Classification and Prediction of Skyrmion Material Based on Machine Learning.

The discovery and study of skyrmion materials play an important role in basic frontier physics research and future information technology. The database of 196 materials, including 64 skyrmions, was established and predicted based on machine learning. A variety of intrinsic features are classified to optimize the model, and more than a dozen methods had been used to estimate the existence of skyrmion in magnetic materials, such as support vector machines, -nearest neighbor, and ensembles of trees.

A Recognition Method of Truck Drivers' Braking Patterns Based on FCM-LDA2vec.

Taking truck drivers' braking patterns as the research objects, this study used a large amount of truck running data. A recognition method of truck drivers' braking patterns was proposed to determine the distribution of braking patterns during the operation of trucks. First, the segmented data of braking behaviors were collected in order to extract 25 characteristic parameters.

SERS-active nanocellulose substrate via in-situ photochemical synthesis.

Surface-enhanced Raman scattering spectroscopy (SERS) is a highly-sensitive technology to detect trace target analytes. Herein, a series of flexible SERS substrate for the detection of malachite green (MG) bactericide were developed via in situ photochemical synthesis of silver nanoparticles (AgNPs) based on two dimentional (2D) nanocellulose film without additional reducing agent. For the first time, silver nanocubes (AgNCs) with sharp edges and corners, which are conductive to the formation of hot spots, were successfully prepared and uniformly loaded on the nanocellulose film by controlling the reaction conditions.

Multifunctional cellulose paper-based materials and their application in complex wastewater treatment.

The rapid and efficient treatment of complex wastewater remains challenging. Herein, green paper-based materials with high wet strength, good oil-water separation property and high heavy metal ion adsorption capacity were prepared via a facile, cost-effective process. The introduction of amphoteric functional groups not only met the requirements for heavy metal ion adsorption, but also maintained the stable underwater superoleophobic properties of materials a wide pH range.

Flexible 2D nanocellulose-based SERS substrate for pesticide residue detection.

Nanocellulose holds considerable promise as an effective surface-enhanced Raman scattering (SERS) substrate for sensitive detection of trace targets. Flexible and high-sensitivity two-dimensional (2D) SERS substrates based on nanocrystalline cellulose (CNC) film were successfully developed via self assembly of two plasma nanoparticles: gold nanoflowers (AuNFs) and silver-coated gold nanocubes (Au@AgNCs). The loading process allows the precise control of nanoparticle distribution density and uniformity on CNC film, which are closely related to the plasma coupling effect between particles.

Charge transport and extraction of PTB7:PCBM organic solar cells: effect of film thickness and thermal-annealing.

Charge carrier transport in the active layer and charge extraction at the electrode have significant impact on the performance of solar cells. In this study, the effect of active layer thickness and thermal-annealing treatment on the charge transport and extraction performance of PTB7:PCBM organic solar cells was studied comprehensively. Thin films of active layer couldn't utilize enough sunlight, while thick films could bring about large bulk resistance and deteriorate carrier transport.